有机酸对成都平原镉污染土壤的淋洗效果.PDF

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 有机酸对成都平原镉污染土壤的淋洗效果 ∗ 黎诗宏,蒋卉 ,朱梦婷,梁斌,徐志强,户双节 西南科技大学环境与资源学院,绵阳621010 摘　 要　 以成都平原某化工厂附近受 Cd污染的2 种土壤为对象,采用振荡淋洗技术,研究了有机酸在不同浓度、固液比、 -1 振荡时间和复合淋洗条件下对重金属 Cd 的去除效果。 实验结果表明:柠檬酸和酒石酸对 Cd 含量为 22.78 mg ·kg 的 SLT-01土壤具有更好的去除效果,分别达到73%和62% ,而乙酸和草酸的去除能力较低;随着固液比的降低,有机酸对 Cd 的去除率逐步提高;随着时间的增加,Cd 的去除率波动增加;柠檬酸和酒石酸复合淋洗并没有提高 Cd 的去除率;振荡淋洗 前后土壤结构未发生明显变化。 综合考虑土壤中Cd 的去除效果和成本,选择柠檬酸作为最佳淋洗剂;最佳实验条件:溶液 -1 浓度为0.10 mol ·L ,固液比为 1∶20,淋洗时间为8 h。 关键词　 有机酸;镉;淋洗;污染土壤;去除率;成都平原 中图分类号　 X53　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-3227-06　　 DOI　 10.12030/ j.cjee.201606135 Leaching effect of organic acid on soil polluted by cadmium in Chengdu Plain ∗ LI Shihong,JIANG Hui ,ZHU Mengting,LIANG Bin,XU Zhiqiang,HU Shuangjie School of Environment and Resources,Southwest University of Science and Technology,Mianyang 621010,china Abstract　 In this paper,with the oscillating washing technology,two kinds of contaminated soil which collected from the surroundingsof a chemical plant in Chengdu Plain were as samplesto study the removal effectsof the or- ganic acid on the heavy metals Cd under the condition of different concentration, solid-liquid ratio,oscillating time and compound washing. It showed that the citric acid and the tartaric acid had a better removal effect on the -1 SLT-01 soil whose Cd content was 22.78 mg ·kg . The removal rate reached 73% and 62% ,respectively. Whereas the removal ability of acetic acid and oxalic acid was not good. The removal rate of the organic acid on the Cd wasgradually improved asthe solid-liquid ratio reduced. Thefluctuation of