Thepreparationofsilicawhitefromflyashandits培训课件.pptVIP

,, The preparation of silica white from fly ash and its characterization Zhitong YAO1, 2, Jinhui LI1, Meisheng XIA2, Ying YE2 1Department of Environmental Science and Engineering, Tsinghua University, Beijing, China 2Department of Ocean Science and Engineering, Zhejiang University, Hangzhou, China Abstract: The silica white was prepared using fly ash as raw material. It comprised alkaline fusion of fly ash followed by extraction with hydrochloric acid. The acid concentrations, reaction time, S/L ratio and stirring rate on silica extraction efficiency were investigated. The prepared silica white was also characterized by XRD and N2 adsorption-desorption. The results showed that, the extracting rate displayed an increasing trend with the increase of acid concentrations, reaction time and stirring rates. The specific surface area and average pore size of the prepared silica white were 364.8m2/g and 6.02nm, respectively. Keywords: fly ash; silica white; extraction efficiency; hydrochloric acid Introduction Silica white (SiO2·nH2O) is a highly-refined chemical product, with nH2O in the form of surface hydroxyl groups. Its chemical characteristic is stable and possesses excellent properties. Therefore, it has been widely applied in rubberized foot wear, paint, dyes, printing ink, and plastic products. Regarding to the preparation, it is usually prepared by chemical vapor deposition method using silicon tetrachloride as raw material and acid precipitation method using water glass solution and acid as precursors. Experimental 1. Material and methods The fly ash was derived from a thermal power plant in Zhejiang province, China. After pretreatment by froth floatation removing the unburned carbon and floating beads, its chemical components were determined. It consists of following oxides (in wt.%): SiO2 50.5, Al2O3 35.9, Fe2O3 5.3, CaO 4.6, TiO2 1.5, K2O 1.3 and others 0.9. 2. Preparation procedure (1) Activation The ash was mixed with sodium carbonate anhydrous in