材料分析文献报告讲义.pptVIP

材料分析文献报告（纳米光子学中用到的材料测试方法） 姓名：陈义富 学号2015.10.11 1.Optical properties of silver nano-cubes 介绍 金属内部与表面存在大量自由电子, 形成自由电子气团, 即等离子体(plasmon); 而表面等离子体则特指存在于金属表面的自由电子气团. 当入射光与金属纳米结构表面自由电子气团的振动发生共振时就形成了表面等离子体共振(surface plasmon resonance,SPR)。 金属纳米结构的表面等离子体光学在光催化、光学传感、生物标记、医学成像、太阳能电池, 以及表面增强拉曼光谱等领域有广泛的应用前景, 这些功能也和金属纳米结构与光相互作用时产生的表面等离子体共振密切相关。 (a) 电场作用下金属纳米颗粒等离子体振荡示意图 (b) 电场作用下金属-电介质界面等离子体振荡示意图, 电场可以被局域在亚波长尺度内 Synthesis of silver nano-cubes Optical properties is an important property and signature of nanomaterials. Here the silver nano-cubes prepared by chemical reduction method. Silver nano-cubes have been synthesized by reducing AgNO3 with ethylene glycol using poly (vinyl pyrrolidone) (PVP) as a stabilizing agent. Characterization analysis X-ray diffraction studies of the silver nano-cubes have been carried out X-ray diffractometer (XRD). Cu Ka X-rays of wavelength λ = 1.54056 ?. Size and morphology of the silver nano-cubes have been obtained by transmission electron micro-scopy (TEM), operating at an accelerating voltage of 200 kV. (1).X-ray diffraction(XRD) analysis The reflections are indexed as (111), (200) and (220) with the corresponding 2h values of 38.013°, 44.133°and 64.104° respectively. All the reflection peaks as obtained correspond to the pure silver metal with face centered cubic (fcc) symmetry. Average particle size has been calculated using Debye Scherrer formula: D = Kλ/bCosh where ‘K’ denotes the Scherrer constant (shape factor) and b is broadening of diffraction line measured at half of its maximum intensity (in radian); λ = 0.1541 nm is the wavelength of the incident Cu K-a radiation; and h is Bragg diffraction angle (in degree)，the calculation the average crystallite size of the silver nano-cubes is found to be 86 nm (approx). (A) TEM micrograph of silver nano-cubes, with (C) High resolution TEM image, (B) Particle size distribution histogram and (D) SAED pattern of silver nanocrystals (2).Hig