硫化物纳米材料的制备及其光催化性能研究-无机化学专业论文.docxVIP

P墨t59075半导体硫化物纳米柑料的删备及其光催化性能副『究 P墨t59075 半导体硫化物纳米柑料的删备及其光催化性能副『究 摘 要 中文摘要 本文主要研究制备半导体纳米硫化物及有机一无机杂化硫化物材料的儿种新方 法。首先以三硫代碳酸钠为土要原料，合成了前驱物CdCS，、【Cd(en)，]cs，和PbCS3。 这些前驱物在适当温度和压力下分解，即得CdS、PbS纳米粉体。用X．射线粉术衍射、 ， 透射电镜、扫描电镜，对产物的组成、大小、形貌进行了表征。I结果表明：纳米CdS ＼ 为粒度分布均匀的六方品形，晶粒大小约为20nm；纳米PbS为粒度分布均匀的立方 型晶型，粒径大小约为20nm。该方法经济、简便、产物无明显团聚现象，有较好的虑 、 用价值。另外寸7利用溶剂热合成技术，以醋酸锌和硫粉为原料，在二乙烯三胺或正丙 ， ● 二胺溶剂中，制备了经有机胺改性的新型硫化物材料： 【(ZnS)2NH2(cH)3NH2]。和 - 、 【(ZnS)：，(NH2CH：CH)：NH：】。。产物难溶r水和各种有机溶剂，是一类高聚配合物，并 经红外、X．射线粉未衍射、傅立叶拉曼、透射电镜、热重分析和元素分析等方法表征。 一 0实验表明 该类新材料对活性紫x．2R染料的有较好的光催化降解效果，催化剂经十多 t 次重复使用，催化效率基本不变。j ／ 关键词：硫化物；纳米材料i配僻化合物i正内二胺’二乙烯三胺，光催毁 李文戈 指导教师：戴沽 _ ＼‘ 兰量!苎堕些塑塑鲞丝!!塑塑墨丝丛生堡些苎壁型壅 兰量!苎堕些塑塑鲞丝!!塑塑墨丝丛生堡些苎壁型壅 塑 矍 Abstract New methods for preparing nanoscale sulfides and organic-inorganic hybrid sulfides were investigated．Nanoparticles of CdS and PbS were obtained by decomposing precursors of CdCS3，【Cd(en)3]cs3 and PbCS3 respectively，at a constant temperature and pressure．The precursors were synthesized simply by mixing solutions of Na2CS3 and CdCl92．5H20 or Pb(Ac)2．3H20 at room temperature．SEM，TEM and XRD were used on characterization of the products．The results showed that the CdS and PbS nanoparticles are hexagonal and cubic structure respectively with uniform size about 20 nm．On the other hand，novel materials of 【(ZnS)2NH2(CH2)3NH2】*and[(ZnS)2 5NH(CH2CH2NH2)2k were synthesized from elemental sulfur and zinc(It)saIt m I．3-propaned(amine and diethylenetriamine by solvothermal technique．They were characterized by IR，XRD，FT—Raman and TEM etc．The compounds ‘ are insoluble in water and organic solvents and are considered as organic—inorganic hybrid polymers．The compounds revealed good photocatalytic activity for degradation of a dye， reactive violet X-2R．and keep nearly the same activity after 1 0 times repeated experiments． Key words：sulfide，nanomaterial，coordination compound，diethyIenetriamine 1