离子交换提铀工艺用水闭路循环技术研究-分离科学与技术专业论文.docxVIP

中文摘要 K .11，，:.， 实现工艺水闭路循环使用，避免或减少对环境的污染，一直以来是铀矿水 冶领域的一大技术难题。本试验从采用新型的离子交换树脂和改变淋洗工艺着 手，通过条件试验、台架试验以及现场工业试验验证，确定了其实现的可能性。 试验结果表明: 1) D363B 树脂对青龙铀矿酸法搜出液具有良好的吸附性能，其饱和吸附容 量达到 50mgU/ml (榄)。吸附尾液的铀浓度可控制在 20mg/L 以下。 2) 用碳酸铀溶液作淋洗剂可以满足青龙铀矿铀提取和凹收过程中工艺用水 闭路循环的技术要求，其浓度为 150g/L。该淋洗剂的淋洗效率高，可以获得杂 质含量少的淋洗合格液。 3) 每次淋洗过程中只需要补加 2日V 的碳酸纳溶液作新淋洗剂就可以满足淋 洗的要求。综合整个工艺流程，溶液的循环只在每塔的淋洗过程中补加 2日V 的碳 酸纳溶液作新淋洗剂，这部分溶液对于浸山的循环溶液的体积是很小一部分，可 随鹿弃堆带走，不影响过程洛液的平衡。 4) 使用吸附屁液转型贫树脂的工艺简单，不需要单独配制转型液和转型设 备。 5) NaOH 搭液作沉淀剂可以获得高质蠢的黄饼。 从试验结果可以看出，在不影响整个工艺的效率的前提下，采用离子交换 法实现了从酸性浸出液中提取分离铀过程的工艺水闭路循环，该技术为解决铀矿 采冶过程中的废水污染问题提供了新的思路。 关键询:铀离子交换废水 份 串， 、 ABSTRACT t IJ ， 鼻 (.01 、 It is a great technical problem for a long time in uranium míne and metallurgy to realize its technology eft1uent for recycling application and avoid or reduce to environment pollution. By adoption new kind of íon exchange resin with change and improvement the elution technology in 由is experiment ，it was conformed by conditional experiment，bench scale experiment as wel1 as in plot experiment to realize its feasibility. Experimental results indicate that: D363B resin shows very good adsorption property for the acid leached uranium solution in Qinglong uranium mine. Resin saturation capacity can reach to 50 mg.U/ml(wet). Uranium concen往ation in the after adsorbed solution can be controlled under 20mgll. It can meet the technical requirements for used water closed recycle in recovery uranium process by adoption of sodium carbonate as elution reagent. Sodium carbonate concentration is 150gll. ηl?s elution reagent has high elution efficiency and in 由e richen uranium solution has low impurities. Addition of 2日V sodium carbonate solution as new elution reagent can meet elution requiremen t. As a whole technology process ，in solution recycle 2BV sodium carbonate was added in each tower elution process as new elution reagent.丁bis part solution is very small portion of the recyc1e solution volume，which can be carried out to the d