磷钨酸铈催化剂的制备及催化性能研究-材料工程专业论文.docxVIP

内 内蒙古科技大学硕士学位论文 The optimum reaction conditions above the synthesis of methyl palmitate in the present of CePW12O40 were reaction temperature 67 ℃, acid to alcohol mole ratio 1:12, 4 h reaction time, catalyst dosage is 9% of the quality of palmitic acid; Palmitic acid conversion rate were greater than 96% in the catalyst recrystallization recycling for 10 times. The optimum reaction conditions above the synthesis of palmitic acid and stearic acid in mixed acid methyl ester in the present of CePW12O40 were reaction temperature 67 ℃, acid to alcohol mole ratio of 1:10, 4 h reaction time; The mixed carboxylic acid conversion rate were greater than 96% in the catalyst recrystallization recycling for 10 times. CePW12O40 which was new prepared in contrast with CePW12O40 which was recrystallization after recycling in the synthesis of methyl laurate 10 times by XRD and IR analysis showed the recycling of CePW12O40 is feasible as the structure of catalyst did not change. Key Words：CePW12O40；Catalyst；Cycle；Methyl laurate III PAGE PAGE 1 目 录 摘 要 I AbstractII 引 言 - 1 - 1 文献综述- 2 - 1.1 杂多化合物的发展历史 - 2 - 1.2 杂多化合物的结构- 2 - 1.2.1 Dawson 结构 2:18 系列 - 2 - 1.2.2 Silverton 结构 1:12B 系列- 3 - 1.2.3 Anderson 结构 - 4 - 1.2.4 Waugh 结构 1:9 系列 - 4 - 1.2.5 Keggin 结构 1:12A 系列- 4 - 1.3 杂多化合物的酸性- 6 - 1.4 杂多化合物中水的存在形式 - 7 - 1.5 杂多化合物的氧化还原性- 8 - 1.6 杂多化合物的“准液相”性质 - 8 - 1.7 磷钨酸常用制备方法 - 9 - 1.7.1 经典的化学法 - 9 - 1.7.2 乙醚萃取法- 9 - 1.7.3 离子交换法- 10 - 1.7.4 电渗析法- 10 - 1.7.5 白钨酸沉淀法 - 11 - 1.7.6 其它方法- 11 - 1.8 杂多化合物的应用- 11 - 1.8.1 磷钨酸及其盐在酯化反应中的应用- 12 - 1.8.2 磷钨酸及其盐在脱水和水合反应中的应用 - 13 - 1.8.3 磷钨酸及其盐在 Friedel-Crafts 酰化反应中的应用- 13 - 1.8.4 磷钨酸及其盐在其它有机反应中的应用- 14 - 1.9 问题的提出和研究内容 - 14 - 1.9.1 问题的提出- 14 - 1.9.2 研究内容- 15 - 2 实验试剂与设备及分析测试方法 - 16 - 2.1 实验试剂 - 16 - 2.2 实验设备 - 16 - 2.3 实验表征及测试方法 - 17 - 2.3.1 XRD 分析- 17 - 2.3.2 TG-DSC 分析 - 17 - 2.3.3 红外光谱分析- 18 - 2.3.4 比表面积分析- 18 - 2.3.5 核磁共振分析- 18 - 2.3.6 料液浓度测定- 18 - 2.3.7 羧酸转化率测定方法- 19 - 3