气质分析解析 低温煤焦油中的芳香族化合物资料精.pdfVIP

Energy Fuels 2010, 24, 5533–5538 : DOI:10.1021/ef1007352 Published on Web 09/08/2010 Identification of Dihydroxy Aromatic Compounds in a Low-Temperature Pyrolysis Coal Tar by Gas Chromatography-Mass Spectrometry (GC-MS) and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) Quan Shi,*,† Yan Yan,† Xiaojiao Wu,† Shuyuan Li,*,† Keng H. Chung,‡ Suoqi Zhao,† and Chunming Xu† †State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102200, China, and ‡ Well Resources, Incorporated, Edmonton, Alberta T6R 1J8, Canada Received June 12, 2010. Revised Manuscript Received August 24, 2010 Dihydroxy aromatics in coal tar undergo rapid coupling reactions with each other and with some coal- derived species during coal pyrolysis and liquefaction. However, only limited information on the structure of dihydroxy aromatics is known. In this study, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) and gas chromatography-mass spectrometry (GC-MS) were used to characterize the dihydroxy aromatics in a low-temperature pyrolyzed coal tar and its distillate and residue fractions. Negative-ion electrospray ionization (ESI) FT-ICR MS spectra of coal-tar-derived samples had low molecular masses and narrow mass ranges. Negative-ion ESI is extremely selective for the dihydroxy aromatics present in coal tar. The O2 class species had the highest ion intensity among the species in the negative-ion FT-ICR mass spectrum for each sample. Dihydroxy compounds with an aromatic core structure of benzene, indan, biphenyl (and/or acenaphthene), and naphthalene were identified in the d