镁质熔剂性球团性能及其原料特性研究.docxVIP

镁质熔剂性球团性能及其原料特性研究 刘连继，肖洪，高冰，张文强，李晓云 (河钢集团唐钢公司总工办，河北唐山063000) 摘要：对镁质熔剂性球团性能及其原料特性进行了分析评价，依托现有原料 条件，进行了镁质熔剂性球团的生产。结杲表明，铁精粉及添加剂性能均能 满足生产要求，其中，矿粉3中SiO2含量仅为1.32%, MgO含量3.33%,但 粒度较粗，因此，配比不宜太高。与普通酸性球团相比，镁质熔剂性球团冶 金性能得到全面改善，还原性提高9.7%,还原膨胀指数降低5%,荷重软化 开始温度和终了温度分别提高27°C和28°C,开始滴落温度提高25°C,滴落 区间降低33°C,特征值降低到240 kpa-°Co 关键词：原料特性；添加剂；球团；冶金性能 Study on Properties of Magnesian Fluxed Pellets and Its Raw Materials LIU Lian-ji, XIAO Hong, GAO Bing, ZHANG Wen-qiang, LI Xiao-yun (Chief Engineer Office, HBIS Group TangSteel Company, Tangshan 063000, Hebei, China) Abstract: The properties of magnesian fluxed pellets and its raw materials were tested and evaluated. And the magnesian fluxed pellets were manufactured under the condition of current raw materials. It is shown that the properties of powdered iron and additive can both meet production requirement. The SiC^content of fine ore 3 was only 132% and the MgO content was 333%. However, the ratio of fine ore 3, which has coarse granularity, should not be so high. Compared to the normal acid pellets, the properties of magnesian fluxed pellets were nearly improved totally. The reduction index was increased 9.7%, the reduction swelling index was decreased 5%, the initial and final softening temperature with load were increased 27 °C and 28 °C respectively, the start dropping temperature was increased 25°C，the dropping temperature range was decreased 33°C and the characteristic value was 240 kpae°C. Key Words: raw material property; additives; pellets; metallurgical property 1引言 提高高炉入炉球团矿配比、降低烧结矿配比是缓解当前国内口益严峻的环保 形势的有效方法⑴。同时，生产球团矿还可以更好的利用国内粒度较细的磁 铁矿粉叫 研究表明，添加含CaO利MgO的熔剂可以改善球团矿成分和冶 金性能，为提高球团矿在高炉屮的配比提供条件3〕。因此，本文对当前原料 条件进行了分析评价，并对生产得到的镁质熔剂性球团性能和微观结构进行 研究，为球团在高炉中的使用提供参考依据。 2镁质熔剂性球团原料特性及评价 2.1铁精粉 （1）铁精粉矿物组成及成分分析 表1所示为三种造球用铁精粉的矿物组成，可以看出，三种铁精粉主要矿物 组成为磁铁矿，其中矿粉1、矿粉2和矿粉3中磁铁矿的含量分别为65.46%、 63.62%和63.10%。F5O4在焙烧中氧化成F?03并伴随晶型转变，能更好的 构成晶桥。同时氧化放热，能耗较低，球团质量也较好。 表1铁精粉矿物组成/% 铁精粉 磁铁矿 碳酸铁 硫铁矿 赤、褐铁矿 硅酸铁 矿粉1 65.46 0.085 0.030 0.44 0.25 矿粉2 63.62 0.17 0.34 1.93 0.40