不同工艺制备蜜胺型高效减水剂的研究.pdf

不同工艺制备蜜殷型离效减水剂韵研究 魏民，邱学青，易聪华，杨东杰 (华南理工大学化学与化工学院 广东省绿色化学品技术重点实验室，广东 广州 510640) 摘要 ：分别采用一步法、两步法、置步法和四步法工艺在8O℃下合成 了磺化蜜胺脲醛树脂减水剂，并研究其减水、增强性能， 采用 IR、GPC、SEM等测试手段研究了减水剂的结构特征及其减水、增强作用机理。结果表明，一步法合成的减水剂无减水增强性 能，两步法合成的减水剂储存稳定性差，三步法和四步泫合成的减水剂在掺量为O．5％时水泥净浆流动度大于 230mm，且贮存 3个 月后减水性能保持不变。TR测试结果表明，三步法与四步法合成的减水剂具有相同分子结构，二步法工艺更为简单，其产品的数均 分子量 为4843，重均分子量 为5131，掺量为 1．0％时硬化砂浆28d抗压比达 190％。 关键词：磺化蜜胺脲醛树脂；混凝土减水剂；作用机理 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2008)10～0058—05 Study on preparation ofmelaminetype superplasticizer by differentprocess E1Min，QIUXueqing，YIConghua，YANGDongfie (SchoolofChemistry andChemicalEngineering，GnangdongProvincialLaboratory ofGreenChemicalTechnology， South ChinaUniversity ofTechnology，Guangzhou 510640，Guangdong，China) Abstract：Sulf0natedmelamineureaformaldehyde (SMUF)resinwaterreducingagentwassynthesized separatelybyprocessof one-step，two—step，three—step and four—step at80 ℃ Its performance of water reducing and enhancementwere studied．The structuralfeature ofwaterreducing agentand itswater reducing and enhancementmechanism were studied by means ofIR，GPC and SEM．The resultsshow thatthewaterreducingagentsynthesized by one-step processhasno waterreducing and enhancement property：and thatsynthesizedby two-stepprocesshaspoorstorage stability；and thatsynthesizedby three—step(SMUF一3) orfour— step(SMUF-4)processcankeepthesaulewaterreducingperformanceafter3monthsstorageandwith addingamountof O．5％ the neatcementpastefluidityisOver230Film．ThetestresultbyIR indicatesthatSMUF一3andSMUF一4havethesamemolecular structure，and three-step process is simple，its product number average molecular weight M is 4843 and the weight average molecularweightMwis5131．Thecompressivestrength ratioofhardenedmortaris 190％ at28dwhen ad