二氧化硫的双语教学(省常中-房寿高).pptVIP

二氧化硅与二氧化碳的比较 默写方程式 1.用氨水吸收尾气中的SO2 2.SO2使紫色石蕊试液变红的原因 3.除去CO2中的SO2 4.等物质的量的Cl2和SO2通入水中 5.SO2和H2S气体混合产生淡黄色固体 * Sulfur dioxide 江苏省常州高级中学 房寿高 一、Preparation of sulfur dioxide 二、Physical properties of SO2 Under normal circumstances ，sulfur dioxide is a kind of colorless gas with a very pungent ([‘p?nd??nt]刺激性 )odour . Its density is more than air. From the preparation, what physical properties can you get? Easily soluble in water(1:40). Easily liquefied ,poisonous gas under pressure. Is it soluble in water? 三、chemical properties of SO2 let’s guess 1. Like CO2, SO2 is an acidic oxide With salt with water With base With basic oxide SO2 CO2 CaO＋SO2 CaSO3 高温 CO2 ＋2NaOH＝ Na2CO3+H2O SO2 ＋2NaOH＝ Na2SO3+H2O CO2 ＋Na2CO3+H2O＝ 2NaHCO3 Some other important chemical equations. SO2+NaOH=NaHSO3 （excess） Like CO2,If you Pass SO2 through limewater[ Ca(OH)2],the limewater turns cloudy. Continuing passing SO2 will eliminate the cloudy condition . SO2+H2O+CaSO3 = Ca(HSO3 )2 Calcium bisulfite Enlarge you view stalagmite [st?l?ɡmait, st?l?ɡmait] 石笋；石笋状 stalactite [st?l?ktait, st?l?ktait] 钟乳石 SO2+Na2CO3= （insufficient ） SO2+2NaHCO3=Na2SO3+2CO2 +H2O （insufficient ） Na2SO3+CO2 SO2+ Na2CO3 (excess） — NaHSO3+CO2 +H2O 2 2 SO2+NaHCO3=NaHSO3+CO2 （excess） — Exercises： To remove the impurity gas of SO2 in CO2 ,which reagent should we choose( ) A. Saturated Na2SO4（aq) B. Saturated NaHCO3(aq) C. SaturatedNaOH(aq) D. Saturated Na2CO3(aq) B SO2 S H2SO4 0 +4 +6 氧化性 加还原剂 还原性 加氧化剂 Prediction：Both as oxidizing agent and reducing agent。 Guess from the valence of sulfur 2、reducibility SO2 Can react with O2、X2 solution （Cl2、Br2、I2）、 H2O2 、 HNO3 、KMnO4(H+)、Fe3+ etc. 2) SO2+Cl2 + H2O= (Br2、I2 similarly） 2SO2+O2 2SO3 1) △ HCl+H2SO4 2 2 Question： Put some SO2(g) into BaCl2(aq),is there any white precipitation [pri,sipi‘tei??n](沉淀） ? Then add some drops of H2O2,