生物柴油的氧化对其燃烧特性的影响.docxVIP

PAGE 10 中国工程热物理学会 中国工程热物理学会 燃烧学 学术会议论文 编号：184363 生物柴油的氧化对其燃烧特性的影响 刘作文a,b 李法社a,b,* 王文超a,b 倪梓皓a,b 陈煜a,b (a.省部共建复杂有色金属资源清洁利用国家重点实验室，昆明理工大学，昆明 650093) (b.昆明理工大学冶金与能源工程学院2，昆明 650093) （ Tel Email:1605827197@） 摘要：本文采用Rancimat法加速生物柴油的氧化，利用OH-PLIF系统分析研究生物柴油的氧化对其燃烧特性的影响。研究结果表明：随着当量比的增大，；生物柴油的层流预混火焰传播速度呈现先增大后减小的趋势；CO和CO2的排放量之比[CO]/[CO2]先增大后减少；NO排放量逐渐减少。生物柴油的氧化对其燃烧特性有重要的影响，随着氧化时间的增加，火焰OH-PLIF信号增强，生物柴油的层流预混火焰传播速度逐渐增大，在氧化24h，其速度达到最大值，为61.25cm/s； [CO]/[CO2]先减少后增大；NO排放量逐渐增大。 关键词：生物柴油；氧化；OH-PLIF；火焰传播速度；NO Oxidation of biodiesel on its combustion characteristics Zuowen Liua,b Fashe Lia,b,* Wenchao Wanga,b Zihao Nia,b Yu Chena,b a State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province, Kunming 650093, China; b Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China *Corresponding author: Fashe Li; Tel: +86 E-mail:liuzuowen3@163.com Abstract:In this paper, the oxidation of biodiesel was accelerated by Rancimat method, and the effect of biodiesel oxidation on its combustion characteristics was analyzed using OH-PLIF system. The results show that: with the increase of equivalence ratio, the laminar premixed flame propagation speed of biodiesel first increases and then decreases; the ratio of CO and CO2 emissions [CO]/[CO2] increases first. After the increase, the amount of NO emissions gradually decreased. The oxidation of biodiesel has an important influence on its combustion characteristics. As the oxidation time increases, the flame OH-PLIF signal increases, and the laminar premixed flame propagation speed of biodiesel gradually increases, and the speed reaches a maximum at 24 h of oxidation., 61.25cm/s; [CO]/[CO2] decreased first and then increased; NO emission gradually increased Key wo