锂离子电池电滥用过程热行为研究.docVIP

基金项目：本研究得到国家重点研发计划新能源汽车专项（编号2018YFB0104102）和广东省科技计划项目(编号2015B010118001)资助 中国工程热物理学会 燃烧学 学术会议论文 编号：184382 锂离子电池电滥用过程热行为研究 陈才星1，牛慧昌1*，李钊1，莫善军2，黄鑫炎3 1广州中国科学院工业技术研究院 新能源热安全工程技术研究中心，广东 广州 511458 2 中山大学 工学院 广东 广州 510006 3 香港理工大学 火灾工程研究中心 香港 九龙 (Tel Email: niuhuichang@) 摘 要 采用加速绝热量热仪分析锂离子电池在初始温度为30℃及80℃绝热环境下过充电和过放电的热行为，发现电池在30℃时0.5C及1C过放电无热失控风险， 80℃过放电电池安全阀打开，存在热失控可能；电池在30℃及80℃时0.5C及1C过充电均发生热失控并起火爆炸。采用恒温箱分析锂离子电池在散热条件电滥用热行为，发现80℃过放电可通过环境散热避免电池安全阀开启；而在过充电过程采用30℃恒温散热及过充电阶段0℃低温散热均不能抑止电池热失控。 关键词 锂离子电池 过充电 过放电 热失控 Thermal behaviour study of lithium ion battery during electric abuse process Chen Caixing1, Niu Huichang1*, Li Zhao1, Mo Shanjun2，Huang Xinyan3 1. Institute of Industry Technology, GuangzhouChinese Academy of Sciences, Guangzhou, 511458，China 2. School of Engineering, Sun Yat-sen University, Guangdong Guangzhou 510006, China 3. Department of Building Services Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong Abstract EV Accelerating Rate calorimeter (EV-ARC) was utilized in this work to analyze thermal behaviours of lithium ion battery during electric abuse process in the adiabatic condition, with the initial temperature of 30 oC and 80 oC. The results indicate that during the overdischarge process, no thermal runaway risk appears when the initial temperature is 30 oC, while pressure relief valve is finally opened at the initial temperature of 80 oC, and thus leading to a high risk of thermal hazzard. In the overcharge process, thermal runaway happens whatever the charge rate is 0.5C or 1C, and the initial temperature is 30 oC or 80 oC. Thermostat was applied to study thermal behaviours of lithium ion battery during electric abuse process in the heat dissipation condition. The results show that the opening of pressure relief valve can be restrained by heat dissipation in the overdischarge process, while the