基于PL-Raman光谱分析的煤质快速检测方法研究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184192 基于PL-Raman光谱分析的煤质快速检测方法研究 刘佳薇，徐俊，许凯，何立模，苏胜，汪一，胡松，向军* （华中科技大学煤燃烧国家重点实验室，武汉 430074） (Tel: 0278313, Email: xiangjun@hust.edu.cn) 摘 要 本文研究了15种典型中国原煤的PL-Raman光谱，提出了三个能代表光谱特性的特征参数kCE、kCF和IC/G，并建立了特征参数与水分、挥发分以及燃烧着火温度和燃尽温度的定量关联。结果表明：煤的荧光特性由水分和挥发分共同决定，随水分和挥发分增加，荧光特性显著增强。特征参数与煤中的挥发分、碳氢比和燃烧特征温度间存在良好的数学关联，拟合系数高于0.8，可用于煤质特性和燃烧特性的快速检测。最后，提出了 关键词 PL-Raman；煤结构；煤质；反应性；快速检测。 Research on rapid evaluation of coal property using PL-Raman Spectroscopy Liu Jiawei，Xu Jun，Xu Kai，He Limo，Su Sheng，Wang Yi，Hu Song，Xiang Jun基金 基金项目：国家重点研发计划（2017YFB0601802）；中国博士后科学基金2018M630858；国家自然科学基金51576072） （State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong university of Science and Technology, 430074 Wuhan, Hubei, China） (Tel: 0278313, Email: xiangjun@hust.edu.cn) Abstract In this study, PL-Raman spectra of 15 kinds of typical Chinese raw coals were obtained and three characteristic parameters were proposed to represent the spectral characteristics, which were kCE、kCFand IC/G. Quantitative relationships were set up between those parameters and coal property as well as coal combustion characteristics. The results indicate that the fluorescence characteristics of coal are synthetically determined by moisture and volatile content in coal. The fluorescence intensity increases apparently along with the increase of moistures and volatiles. In addition, there are fairly good relationships between parameters kCE、kCF、IC/G and the content of volatile, C/H ratio, ignition temperature and burnout temperature with R2 above 0.8, which can be applied as a probe for coal property and combustion characteristics. This study provided a new method for rapid evaluation of coal propert Keywords PL-Raman；Coal structure；Coal property；Reactivity；Rapid evaluation 0 前言 根据中国国家能源局的预测，到2050年，煤炭仍将是我国主要的一次能源，燃