高温烟气中高岭土捕集KOH的模型研究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184424 高温烟气中高岭土捕集KOH的模型研究国家重点研发计划项目 国家重点研发计划项目(2016YFB0600601)资助 郑传杰,盛昌栋※ (东南大学，能源与环境学院，南京 210096) (TelEmail:920343372@) 摘 要 针对煤粉和生物质燃烧烟气中碱金属K气体的吸附控制，采用一维柱塞流反应器模型探究高岭土吸附KOH的影响因素。将模型预测与实验值对比检验模型合理性，并利用模型计算探究高岭土添加量及KOH浓度对高温烟气中K的吸附及颗粒物生成的影响。结果表明，在模型计算高岭土添加量及KOH浓度范围内，单位质量高岭土吸附K的速率及捕集K的量均随高岭土添加量的增加而减小，随KOH浓度的增大而增大；当烟气中K/(Al + Si) ≤ 0.30时，KOH的均相成核和异相凝结可忽略不计，即通过高岭土的吸附基本可完全抑制碱金属向颗粒物的迁移、转化。 关键词 细颗粒物；碱金属前驱物；高岭土；吸附反应；数学模型 Model Study on KOH Capture by Kaolin in High Temperature Flue Gas ZHENG Chuan-Jie SHENG Chang-Dong※ (School of energy and environment，Southeast university， Nanjing 210096，China) (Tel: Email: 920343372@) Abstract: In order to understand controling the alkali metal gas of K after the combustion of pulverized coal and biomass, modeling study was conducted to investigate the influence factors of KOH adsorption by kaolin with a one-dimensional plug flow reactor model. After comparing the model predictions with the experimental data to verify the rationality of the model, the influences of the amount of kaolin addition and KOH concentrations on the capture of K and depression of particles formation were explored by model calculations. The results showed that the adsorption rate and capture amount of K by unit mass of kaolin decreased with the increase of the addition of kaolin, and increased with the increase of KOH concentration. The homogeneous nucleation and heterogeneous condensation of KOH were negligible when the molar ratio of K/(Al + Si) was less than 0.30 in the flue gas, which meant that the migration and transformation of alkali metal into fine particulate matters could be completely inhibited by the adsorption of kaolin. Key words: fine particulate matters; alkali metal precursor; kaolin; adsorption reaction; mathematical model 0 引言 煤炭在我国一次能源生产和消费中占据主导地位决定了燃煤为