铝基载体与造孔剂对CaO基小球脱碳性能的影响研究.docxVIP

学术会议论文 编号：184447 铝基载体与造孔剂对CaO基小球脱碳性能的影响研究 童贤靓，刘文强*，陈黔军，陈洪强，杨远东，胡迎超，徐明厚* （华中科技大学煤燃烧国家重点实验室，武汉 430074） （Tel：+868503，Email：wenqiang.liu@） 摘 要 本文通过挤压-滚圆法制备CaO基吸附剂小球，研究铝基载体和造孔剂添加对其脱碳性能的影响。本文选取了四种铝基载体的添加比例，分别为5wt%、15wt%、25wt%和35wt%。实验结果表明添加25wt%铝基载体的CaO基小球表现出了较好的循环脱碳性能。为了进一步提高吸附剂的脱碳性能，在添加25wt%铝基载体的吸附剂小球中添加三种生物质粉末充当造孔剂对吸附剂改性。结果表明，添加了三种生物质造孔剂的吸附剂小球都保持着较好的循环吸附性能。 关键字 CO2 吸附；铝基载体；造孔剂；挤压-滚圆；吸附剂小球 Effects of Al inert support and pore-forming materials on CO2 Sorption Performance of CaO Sorbent Pellets Xianliang Tong,Wenqiang Liu*, Qianjun Chen, Hongqian Chen, Yuandong Yang, Yingchao Hu and Minghou Xu* (State Key Laboratory of Coal Combustion, Huazhong University of Science Technology, 1037 Luoyu Road, Wuhan 430074, PR CHINA.) Abstract This work studied the effects of the addition of Al inert support and pore-forming material on CO2 sorption performance of CaO sorbent pellets, which were granulated via an extruded-spheronized method. Four proportions of Al inert support including 5wt%,15wt%,25wt% and35wt% have been selected. It was found that the sorbent pellets incorporated with 25wt% Al insert support possessed the optimal performance. In order to further improve the sorption performance of sorbent pellets, three kinds of biomass have been employed as pore-foming materials to further modify the performance of the pellets incorporated with 25wt% of Al insert support. The results indicated that the sorbent pellets modified with the biomass pore-forming materials maintained good cyclic CO2 sorption performance. Key words CO2 capture; Al inert support; pore-forming material; extruded-spheronized; sorbent pellets 基金项目：国家自然科学基金，基金号0 前言 近年来，由于化石燃料的大量燃烧，CO2大量排放所导致的全球变暖等一系列环境问题受到了广泛的关注。因此，碳捕获、利用和封存（CO2 capture, utilization and storage，CCUS）技术被提出以缓解全球变暖 ADDIN EN.CITE EndNoteCiteAuthorMetz/AuthorYear2005/YearRecNum1/RecNumDisplay