笼状钙基吸收剂的可控合成及其碳酸化性能研究.docxVIP

MACROBUTTON MTEditEquationSection2 SEQ MTEqn \r \h SEQ MTSec \r 1 \h SEQ MTChap \r 1 \h 中国工程热物理学会 燃烧学 学术会议论文 编号：184153 笼状钙基吸收剂的可控合成及其碳酸化性能研究 陈健，段伦博*，卞若愚，谭茗月，石田，卢欲晓 （东南大学能源与环境学院能源热转换及其过程测控教育部重点实验室，南京 210096） (Tel: 025Email: duanlunbo@seu.edu.cn)? ? 基金项目：国家重点研发计划项目(2016YFE0102500-06-01) 摘 要 采用模板法制备钙基吸收剂，研究了钙基前驱体浓度、模板剂粒径、煅烧条件对吸收剂形貌和结构的影响。结果表明，选择T-3作为模板剂，添加尿素并通过从室温慢速升温至800°C煅烧去除模板剂可以制备出具有笼状结构的钙基吸收剂。根据SEM、TEM和XRD的表征结果，提出了尿素辅助下，笼状钙基吸收剂的形成机理。脱碳实验表明，笼状钙基吸收剂的首次CO2吸附量接近理论值（0.772gCO2/g吸收剂），15次循环后的碳酸化性能相比石灰石提高了85.9%。 关键字 模板法；水热法；笼状材料；钙循环；CO2捕捉 Investigation on Accurate Control of Cage-like CaO Hollow Spheres and their CO2 Capture Performance Chen Jian, Duan Lunbo*, Bian Ruoyu, Tan Mingyue, Shi Tian, Lu Yuxiao (Key Laboratory of Energy Thermal Conversion and Control Ministry of Education School of Energy and Environment Southeast University Nanjing, 210096) (Tel: 025 Email: duanlunbo@seu.edu.cn) Abstract: Templating method was used to synthesize CaO-based sorbent in this work. The influence of calcium precursor concentration, size of template, and the calcination condition on the morphologies and the structure of as-synthesized sorbents was investigated. The result shows that, CaO hollow spheres with unique cage-like structure can be obtained when T-3 was selected as the template, and the removal of template was conducted under a slow heating rate from room temperature to 800°C with the presence of urea. The formation mechanism of cage-like CaO hollow spheres with the assistance of urea was also proposed, on the basis of SEM, TEM and XRD results. Furthermore, cyclic CO2 capture tests showed that, the initial CO2 uptake of cage-like CaO hollow spheres was close to the theoretical value. And the CO2 capture performance exceeded the reference limestone by 85.9% after 15 repeated calcination/carbonation cycles. Kew word: templa