表面结构重建泡沫铜催化还原CO2.docVIP

基金项目：中国博士后科学基金（2017M612279），山东大学基本科研业务费资助项目（2017GN008），能源清洁利用国家重点实验室（浙江大学）开放课题项目（ZJUCEU2017010），山东省自然基金（NO.ZR2016EEM17 ） 中国工程热物理学会 燃烧学 学术会议论文 编号：184461 表面结构重建泡沫铜催化还原CO2 刘岩，张梦*，马春元 （山东大学燃煤污染物减排国家工程实验室，济南 250061） (Tel Email163.com) 摘 要 为了增加催化剂比表面积和表面活性位点，进而提高其催化还原CO2活性，将泡沫铜高温热处理进行改性，SEM图显示，高温热处理泡沫铜表面结构被重建，C500,3泡沫铜表面长有丰富的纳米条结构，电化学还原后的热处理泡沫铜表面的纳米条结构上生成大量纳米颗粒，表面结构更加粗糙，EDS和XRD图显示，高温热处理后泡沫铜表面被CuO和Cu2O覆盖，电化学还原将大部分CuO和Cu2O诱导还原为Cu晶体，与普通的单质Cu相比，这种诱导还原Cu晶体催化还原CO2活性增加。 关键词 泡沫铜；高温热处理；二氧化碳；电化学还原；诱导还原 Electrocatalysis reduction of CO2 into Chemicals with surface structure reconstructed Cu foam electrode Abstract: In order to increase the ratio surface area and surface active site of catalyst, and then inproving the activity of catalytic reduction CO2, and the pristine Cu foam was modified by high temperature heat treatment. The SEM image showed that surface structure was reconstructed after the high temperature heat treatment. There were planty of namorod structures on the C500,3 Cu foam surface, and there were large number of nanoparticles on the surface of namorod structures of the Cu foam of heat treatment after electrochemical reduction, So the surface structure became more rough. The EDS and XRD graph displayed that the Cu foam surface with high temperature heat treatment was covered by CuO and Cu2O, and most of CuO and Cu2O was induced to be reduced to of Cu crystal after electrochemical reduction. Compared with common elemental Cu, the activity of catalytic reduction of CO2 of the induced reduction Cu crystal increased. Keywords: Cu foam; high temperature heat treatment; CO2; electrochemical reduction; induced reduction 0 前言 当今社会，人类迫切需要解决的两大难题，即全球变暖和矿物燃料的枯竭，利用太阳能等清洁可再生能源将CO2还原到含碳燃料中是解决这两大难题理想的人工技术 ADDIN NE.Ref.{96E5DCC7-92B6-47EC-97BD-7B09F66C000B}[1]，将CO2催化还原为HCOOH、CH4、CH3OH、C2H4等碳氢化合物的过程中，催化剂起着至关重要的作用，催化剂的活性、稳定性和对产物的选择