煤焦燃烧表面气体产物及二次反应探究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184498 煤焦燃烧表面气体产物及二次反应探究 邹仁杰，罗光前*，李显，姚洪 （华中科技大学煤燃烧国家重点实验室，湖北武汉 430074） (Tel: 027 Email: guangqian.luo@hust.edu.cn) 摘要 本文采用自主研发的气体原位采样热重分析仪，对煤焦表面气体产物进行了探究。首先，证实了气体采样热重可以有效减少空间二次反应与扩散作用对测量结果的干扰，实现反应速率与气体产物同步准确测量。然后，研究了温度和氧气对燃烧表面产物的影响，发现了气体产物CO/CO2同时受到表面一次反应与空间二次反应的影响，其中二次反应对温度更加敏感。最后，对煤焦颗粒附近二次反应进行数值模拟研究，建立了颗粒周围气体产物浓度分布预测方程。 关键词 煤焦；燃烧产物；热重；CO/CO2；二次反应 Investigation of the surface gas products during char combustion and secondary reaction Renjie Zou, Guangqian Luo*, Hong Yao （State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Hubei Wuhan 430074)） (Tel: 027 Email: guangqian.luo@hust.edu.cn) Abstract In this paper, a self-developed gas in-situ sampling thermogravimetric analyzer was used to investigate the surface gas products during char combustion. First, it is confirmed that the gas in-situ sampling thermogravimetric analyzer can reduce the disturbances of secondary reaction and diffusion effect on the measurement results, and realize the accurate measurement of reaction rate and gas products simultaneously. Then, the effect of temperature and oxygen concentraion on the combustion surface products was studied. It was found that the CO/CO2 product was affected both by the surface reactions and the secondary reaction. The secondary reaction was more sensitive to temperature. Finally, the secondary reaction of of coal char was studied by numerical simulation, and the prediction eqatuion of gas products concentration distribution near char surface was established. Key words Coal char; Combustion product; Thermogravimetry; CO/CO2; Secondary reaction 基金项目：国家自然科学基金面上项目（No51476065） 0 前言 煤的燃烧过程一般可以分为三个阶段，预热，挥发分燃烧，以及后续煤焦燃烧，其中，与前两个阶段相比，煤焦燃烧阶段持续时间最长，并且在此过程中释放的热量占煤粉总放热量的60-95%。因此，煤焦的燃烧效率决定了煤的利用效率，对煤焦燃烧过程的研究至关重要[1-2]。 煤焦燃烧主要涉及到的宏观化学反应如下： C+O2→CO2 C+1/2O2