单颗粒煤矸石的燃烧特性研究.docxVIP

中国工程热物理年会 燃烧学 学术会议论文 编号：184506 单颗粒煤矸石的燃烧特性研究 基金项目：国家自然科学基金项目（NO 基金项目：国家自然科学基金项目（NO 王新华，林其钊*，王成鑫，李奉誉，雷言言 中国科学技术大学工程科学学院热科学与能源工程系，安徽合肥，230027 ( Tel:0551 Email: qlin@ustc.edu.cn) 摘要: 本文首先研究了煤矸石在空气条件下的热重特性,基于Arrhenius公式，利用Flynn–Wall–Ozawa方法对样品的动力学参数进行求解。然后在立式加热炉中，研究了单颗粒煤矸石的着火机理。结果表明，煤矸石的失重曲线和失重速率曲线随着加热速率的增加而向右平移，且当样品失重转换率由0.2增大到0.9时，活化能由247.4 KJ/mol减小到160.8 KJ/mol。立式加热炉中，煤矸石颗粒的着火类型分为均相着火和非均相着火以及均相、非均相同时着火，不同的气流流速、温度和氧浓度都会影响着火的类型。 关键词：煤矸石； 活化能； 单颗粒； 着火机理； Investigation on combustion characteristics of coal gangue pellet Xinhua Wang, Qizhao Lin*, Chengxin Wang, Fengyu Li, Yanyan Lei Department of Thermal Science and Energy Engineering, University of Science and Technology of China, Hefei 230027, China ( Tel:0551 Email: qlin@ustc.edu.cn) Abstract: The thermogravimetric characteristic of coal gangue was firstly investigated with air condition, based on the Arrhenius formula, the kinetic parameters of the samples were calculated by Flynn–Wall–Ozawa method. The ignition mechanism was then studied in a drop tube furnace. The results show that the TG/DTG curves shifted to right when the heating rate increased, the activation energy decreased from 247.4 KJ/mol to 160.8 KJ/mol when the conversion rate increased from 0.2 to 0.9. The ignition mechanism was classified into homogeneous, heterogeneous and hetero-homogeneous ignition, and it was affected by gas flow rate, temperature and the oxygen concentration. Key words: Coal gangue; Activation energy; Single pellet; Ignition mechanism 0 前言 煤矸石是煤开采和选煤过程中的一种废弃产物，一直被认为是一种垃圾燃料。但是由于煤矸石占据了整个煤产量的10-15% ADDIN EN.CITE EndNoteCiteAuthorLiu/AuthorYear2010/YearRecNum2/RecNumDisplayText[1]/DisplayTextrecordrec-number2/rec-numberforeign-keyskey app=EN db-id=sasvzprwbx2av2eaxpdprs9dsavaveaw00z02/key/foreign-keysref-type name=Journal Article17/ref-typecontributorsauthorsau