提高苯丙乳液转化率的研究.pdf

提高苯丙乳液转化率的研究 燕冲，张心亚，黄洪，陈焕钦 (华南理工大学化学工程研究所，广东 广州 510640) m 摘要：采用乳液聚合工艺，合成了苯乙烯一甲基丙烯酸一丙烯酸丁酯一甲基丙烯酸甲酯四元共聚乳液，系统研究了乳化剂体系、 o 引发剂体系、聚合工艺、聚合温度对乳液聚合转化率的影响。实验结果表明，采用阴非复配乳化剂体系、半连续饥饿态加料方式、聚 c ● 合温度8O℃、后补加氧化还原引发剂，可使乳液聚合转化率得到显著的提高。 . 关键词：苯丙乳液；乳液聚合：转化率；乳化剂；聚合工艺 g 中图分类号：TQ331．4 文献标识码：A 文章编号：100l一702X(2007)12—0022—04 n o Study on improving conversion rate ofstyrene／acrylate emulsion l YAN Chong，ZHANG Xinya，HUANG Hong，CHEN Huanqin u (InstituteofChemicalEngineering．SouthChinaUniv．ofTech．，Guangzhou510640，Guangdong，China) h z Al~tractslStyrene／acrylateemulsionWaSsynthesized byemulsionpolymerization．with styrene (St)．methacrylicacid(MAA)， . butylacrylate(BA)andmethylmethacrylate (MMA)aS copolymerizationmonomers．Theeffectsofemulsifiersystem，initiatorsystem， w polymerization process and polymerization {emperaturd on conversion rate ofemulsion polymerization were systemically investigated． w Theexperimentresultsshow thatemulsifiersystem。semi—continuousemulsionpolymerization．polymerization temperatureat80℃ ， w adding oxidation—reduction initiatorcould improvetheconversionrateofemulsion polymerization dramatically． Keyword~：styrene／acrylateemulsion：emulsionpolym