水泥窑共处置过程中砷挥发特性及动力学研究-中国环境科学.pdf

中国环境科学 2014,34(6) ：1498~1504 China Environmental Science 水泥窑共处置过程中砷挥发特性及动力学研究 崔敬轩 1,2,闫大海 2*,李 丽 2,王 琪 2 (1.北京科技大学土木与环境工程学院,北京 100083 ；2. 中国环境科学研 究院固体废物污染控制技术研究所,北京 100012) 摘要：针对不同形态的含 As 化合物开展了热重实验、熟料煅烧以及熟料消解实验,研究了水泥窑共处置过程中砷在等温条件下随时间的 挥发特性和可能的化学反应.结果表明,不同化学形态的砷挥发规律不尽相同,砷酸钠在水泥生产涉及的温度区间基本不挥发;硫化亚砷在 水泥窑共处置的过程中,砷的挥发率随时间逐渐增大,25min 以后基本不再挥发,低于 1000℃时,砷的挥发率随温度的升高而增大,但高于 1000℃时,挥发率随温度的增大而减小;亚砷酸钠在 1000℃以上的挥发规律与硫化亚砷类似,挥发率随温度的升高而减小,25min 以后基本不 再挥发.硫化亚砷在 1000℃以下煅烧时,挥发率随时间和温度变化的动力学方程为α =1-exp[-1.77exp(-3158/T)t],可以根据此方程计算不同 温度和停留时间工况下砷挥发的理论值,进而控制含砷废物的投加量,避免对环境造成危害. 关键词：共处置；砷；动力学；危险废物 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2014)06-1498-07 Volatilization characteristics and dynamics research on arsenic during co-processing in cement kilns. CUI 1,2 2* 2 2 Jing-xuan , YAN Da-hai , LI Li , WANG Qi (1.Civil and Environmental Engineering School, University of Science and Technology Beijing, Beijing 100083, China ；2.Research Institute of Solid Waste Management, Chinese Research Academy of Environmental Sciences, Beijing 100012, China). China Environmental Science, 2014,34(6)：1498~1504 Abstract ：Arsenic compounds in different chemical forms were added to cement raw materials to produce clinkers. Thermogravimetric analysis, clinker sintering and clinker digestion were conducted to investigate the volatilization characteristics of arsenic related to time under isothermal conditions and possible reactions during co-processing of hazardous wastes in cement kilns. The results indicate that the volatile law varies with different chemical forms. The volatility of arsenic in sodium arsenate is small within the temperature range pro