有机硅改性酚醛树脂粘结剂的制备与表征.docVIP

PAGE 　50. PAGE PAGE I 摘 要 本文主要介绍了有机硅改性酚醛树脂粘结剂的制备，以及改性后的酚醛树脂的性能。酚醛树脂因为其原料易得，价格低廉，生产工艺和设备简单，而被广泛的应用于粘结剂行业，缺点是其韧性及耐热性较差，限制了酚醛树脂粘结剂在某些特殊领域的应用。而有机硅则因为其结构中含有硅—氧键而具有较好的韧性和耐热性，用有机硅对酚醛树脂进行改性，可以提高酚醛树脂粘结剂的韧性和耐热性。本文介绍了有机硅对酚醛树脂的改性方法，并通过用红外光谱，热重分析，软化点，流动性，抗折强度，抗冲强度，硬度等实验方法进行表征，这几个因素对改性后的酚醛树脂的性能进行了测定和表征，结果表明，用有机硅改性过的酚醛树脂比改性前的酚醛树脂，在韧性和耐热性上均有提高。 关键词： 有机硅 酚醛树脂 改性 制备 表征 Title : The Preparation and the performance of silicone-modified phenolic resin Abstract This paper mainly introduces that the preparation and performance of the silicone-modified phenolic resin binder. Phenolic resin have been widely used in adhesive industry, because it is easy to get, its low price, its simple production technology and equipment, and so on. Drawback is that its poor toughness and heat resistance,and the drawback limits the phenolic resin binder used in some special field of application. But the silicone has good toughness and heat resistance because its structure contains silicon - oxygen bond. Silicone modification of phenolic resin can improve the toughness and heat resistance of the phenolic resin binder. This paper introduces the method of silicone modified phenolic resin, and makes characterization of experimental methods by using infrared spectroscopy, TGA, softening point, mobility, flexural strength, impact strength, hardness,and so on. These factors were measured and characterized on the modified phenolic resin. The results show that the silicone-modified phenolic resin has better abilities in the toughness and heat resistance. Keywords: Silicone-modified Phenolic resin Preparation Performance 目 次 TOC \o 1-3 \h \u 29162 摘 要 I 5288 Abstract II 12702 目 次 III 30299 1 引言 1 5052 1.1 国内外该方向研究的现状 1 32124 1.1.1 胺类改性酚醛树脂 2 11393 1.1.2 硼酸改性酚醛树脂 2 1235