雷射表面重熔法对敏化之不锈钢焊件焊补研究.doc

PAGE PAGE 1 鎳基合金Alloy 82之雷射表面改質技術研究 Rejuvenation of Inconel 82 weldments by Laser surface melting 陳冠聿1, 鄭勝隆2,李驊登 *1, 許家旗1, 曾秉鈞1 K.Y, Chen 1, H. T. Lee *1, C.C. Hsu1, B. C. Tseng 1 1 國立成功大學機械工程學系 2 中科院核能研究所 摘要 本研究針對鎳基合金Alloy 82於銲接過程中產生的析出衰化，而造成耐蝕性下降的問題，以雷射表面重熔技術(Laser surface melting, LSM)嘗試修復。實驗中利用脈衝雷射高速加溫冷卻的特性，於材料表面進行重熔，經微結構觀察不同處理狀態下材料組織差異，再透過抗腐蝕測試分析修復範圍，並使用電化學雙環動電位再活化法評估不同雷射參數之改質效果。 實驗結果發現，經過LSM處理之試件，表面重熔區及熱影響區組織間析出物於雷射高溫歷程中已重新溶回枝晶基地，且在腐蝕測試中未發生沿晶腐蝕(Intergranular corrosion, IGC)及枝晶間孔蝕(Interdendritic pitting)現象。而在電化學測試中，藉由再活化電流與活化電流之比值得到敏化值(Degree of sensitization, DOS)測試結果，進行抗IGC能力的定量化比較，確認LSM處理試件具有較佳抗腐蝕性能。 關鍵詞：鎳基合金、腐蝕測試、雷射表面重熔、 枝晶間孔蝕、敏化值。 Abstract Laser surface melting(LSM) was employed to repair the decayed Alloy 82 weldment. Influence of different laser parameters and the repairing process on interdendritic corrosion were discussed. The width of rejuvenated area was identified by modified Modified Huey test, and the double loop-EPR(DL-EPR) test was used to evaluate the corrosion resistance of each specimen. The interdendritic pitting resistance after LSM process showed remarkable recovery both in melted zone(MZ) and heat affected zone(HAZ). In MZ and HAZ, the Nb-rich phases were resolved, and TiC/NbC or (Nb,Ti)C particles remained existing in the heat affected zone. The results of DL-EPR test also indicated that the laser treated specimens with lower reactivation current and degree of sensitization values (DOS, Ir/Ia), showed higher corrosion resistance. LSM was considered as a practical technique for reducing the corrosion susceptibility in overlaying Alloy 82 weldment. Keywords: Alloy 82、overlaying、interdendritic pitting、Laser surface melting 、DOS 前言 過去1960年代設計之核電廠管路多採用耐蝕能力強的不銹鋼/鎳基超合金為材料，採異材銲接方式接合。核能電廠的循環水管路，因承載具危險性的高溫高壓輻射水，不容許任何管路腐蝕破裂造成洩漏，因而採用較大量的Alloy 82/52/182/152作為銲接熔填、覆銲材料，此類銲件多為管路關鍵零組件，對於系統效能、運轉安全方面有密切影響，因此銲接位置之施工品質、材料力學性能及微結構變化皆為施作上之重要考量 ADDIN EN.CITE ADDIN EN.CITE.DATA [ \o Chang, 2010 #311-6]。當時以鎳基合金Alloy 600及銲條銲線Alloy 82/182為主流，此類合金被認為具有抵