水泥水化浆体中C-S-H微结构脱钙分析.docVIP

水泥水化浆体中C-S-H微结构脱钙分析 水泥水化浆体中 C-S-H 微结构脱钙分析 何真王磊 水资源与水电工程国家重点实验 5 10 15 20 25 30 35 摘要本文采用富里埃红外和高分辨的固体魔角旋转核磁共振技术深入研究了 2 种硅酸盐 水泥水化 3 个龄期浆体中 C-S-H 凝胶的微结构研究发现硅酸盐水泥水化生成的 C-S-H 与矿物 14nm-tobermorite 和 jennite 存在的显著结构差异主要表现在结晶性和硅氧四面体聚 合度两个方面C-S-H 的聚合机理研究表明水泥水化持续生成的水化硅酸根单体 Q0H 与 质子化后的二聚 C-S-H 发生聚合形成少量 C-S-H 长链这是随龄期增加 C-S-H 聚合度升 高的主要原因同时C-S-H 中四配位铝 Al[4] 出现在桥四面体位置其作用类似水化硅酸 根单体桥连二聚 C-S-H 形成更高聚合态的铝硅链上述研究将为揭示 C-S-H 的微结构及 形成机理提供依据 关键词C-S-H微结构聚合度机理核磁共振 中图分类号TQ172 The Decalcification Analysis of C-S-H Microstructure in Hydrated Portland Cement Paste hezhen1 wanglei2 1 State Key Laboratory of Water Resource and Hydropower Engineering Science 2 State Key Laboratory of Water Resource and Hydropower Engineering Science Wuhan University Wuhan 430072 Abstract Effects of decalcification on microstructure of calcium silicate hydrate C-S-H gel in hydrated ASTMⅠcement paste at various ages were studied by X-Ray Fluorescence Spectrometer X-Ray Diffraction Fourier Transform Infrared Spectroscopy and 29Si MAS NMR respectively The results show that the degree of silicate polymerization in C-S-H was largely increased as the bulk CS molar ratio in the hydrated pastes was reduced from 349 to 183 during the leaching process Both dimeric C-S-H and tobermorite-like C-S-H formed in the paste in which the former dominates was decalcified Dimeric C-S-H was protonated after the calcium ions in Si-O-Ca bonds of dimers were removed when decalcified then Si-OH bonds present Polymerization between hydrated monomers Q0H and dimers with Si-OH resulted in a few longer silicate chains Decalcification has less effect on the structure of tobermorite-like C-S-H compared with that of dimers because the central Ca-O layer of tobermorite-like C-S-H was not changed and the tobermorite-like C-S-H was not the dominant phase and had dreierketten of the 3n-1 type Moreover tetrahedrally coordinated aluminum ions occupied more bridging sites on tobermorite-like C-S-H when decalcified the reason o