实用催化第二版课件 教学课件 ppt 作者 高正中 戴洪兴 编著Chapter 2-3.ppt

Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis 对过渡金属的化学性质起主要影响的能带是价带 过渡金属的价电子来自原子的两个电子层（n -1）d1～10和n s1～2。 s能带宽且能级密度的最大值较小，而d能带窄且能级密度的最大值较大，3d能带的能级密度比4s的约大20倍。 Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis 反应物分子活化吸附所需能量与解吸所需能量接近时，催化反应所需的活化能最低。在反应物分子和生成物分子的键能一定时，吸附键的键能要有适宜的值，既不能太小（吸附弱，反应物分子得不到充分活化），也不能太大（吸附强，不利于进一步转化为产物）。 具有良好催化活性的固体表面对反应物分子的化学吸附应该快而不太强。 Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter 2. Adsorption in Catalysis Chapter