抗眩之硬涂聚甲基丙烯酸酯板.doc

中文摘要 本文研究表面具硬塗膜之PMMA板經前處理後，利用含有奈米顆粒之噴塗液進行製備抗眩塗層，並增進抗眩塗層與表面硬塗膜間密著性之方法。 實驗中，利用實驗室自製之L5H-PMMA板與市售之5H-、6H-PMMA板經鹼洗、酸洗(即前處理)，以使表面之硬塗膜產生帶有反應性之官能基。另外，利用FTIR說明其經前處理後其酯基會有部分轉為羧酸基，並利用SEM來觀察表面之硬塗膜經前處理後之表面型態變化，同時藉由比較前處理前、後材料的表面能之變化，以說明前處理作業對具硬塗膜PMMA表面的影響。 同時，利用溶膠-凝膠(Sol-gel)法製備含有帶有環氧基(epoxy group)之奈米顆粒之溶膠溶液，應用奈米粒徑分析儀與FTIR分析奈米顆粒在溶液內進行水解及縮合之反應性與其安定性。另外，將DMA (dimethylaniline)添加於溶膠溶液中以做為環氧基與羧酸基進行反應之觸媒，並進行外觀觀察與FTIR分析，以說明DMA之添加對溶膠溶液之穩定性之影響。將製備所得之含奈米顆粒之噴塗液以噴塗法將其噴塗於經前處理與未經前處理之具硬塗膜PMMA板上，經乾燥可製得抗眩膜層。應用SEM與OM觀察噴塗次數對其所形成之抗眩膜層表面型態及抗眩能力間之關係。最後並藉由添加不同種類之PU樹脂來探討其對抗眩膜層之影響。 實驗結果顯示，表面具硬塗膜之PMMA板經由前處理後，可與所製備帶有環氧基團之奈米噴塗液形成良好之密著性，同時所形成之抗眩膜層具有優異之解析性與透光性。因此，經由本研究方法可簡易地製備具抗眩之硬塗聚甲基丙烯酸甲酯板。 英文摘要 In this study, the nano-particle containing spray solution was prepared via a sol-gel process, and sprayed onto a pre-treated hard coating PMMA sheet to form an anti-glare layer, and methods for improving the adhesion between anti-glare layer and hard coating film surface were also proposed. Experimentally, the surface of hard coating film, including that of the lab-made L5H- and the commercialized 5H-, 6H- PMMA sheet, were surface pre-treated by alkali and acid solutions to produce a reactive functional group on the surface after the pretreatment. FTIR analysis for the ester group changing to carboxylic acid group, SEM image of surface morphology change for the hard coating film after pretreatment, and surface free energy calculation were used to describe the effects of pretreatment. Sol solution was prepared through the sol-gel procedure to obtain the epoxy-group-containing particles dispersed in a buffered solution. The nano-particle size analyzer and FTIR were used to monitor the sol-gel process proceeding and the solution stability. Additionally, the catalyst N,N-dimethylaniline (DMA) was added to the sol solution to be a catalyst for accelerating the reaction between the carboxylic and epoxy groups, and its effect on the sol solution stability was also monitored through the FTIR and nano-particle size analy