钙钛矿催化剂提升POC污染物净化性能研究.pdf

钙钛矿催化剂提升POC污染物净化性能研究 管文军 宋崇林 张清茂 郝斌 吕刚 吴少华 （天津大学内燃机燃烧学国家重点实验室 300072） 摘 要：通过发动机台架试验研究了涂敷La Ce Mn Bi O 催化剂的微粒氧化催化器（POC ）在真实柴油机排气条件下对颗 0.8 0.2 0.7 0.3 3 粒物等柴油机排放污染物的净化性能。结果表明：POC与商用柴油机氧化催化器（DOC ）联用后对HC和CO的去除率达到90% 以上；对PM 的质量去除率随催化剂负载量的增加而提高；在2510r/min 、100%负荷运转状态下，POC 20对PM 的净化效率为89.8%， 其中由于氧化作用产生的PM净化效率为38.7% 。以上说明，La Ce Mn Bi O 催化剂具有良好的柴油机颗粒物净化性能，具 0.8 0.2 0.7 0.3 3 有替代商业POC 中贵金属催化剂的潜力。 关键词：微粒氧化催化器；钙钛矿；催化氧化；柴油机；颗粒物 中图分类号： TK421.5 文献标识码：A Enhanced Effect on Emissions Reduction of Particulate Oxidation Catalyst (POC) by 1 v Perovskite Catalysts 5 3 GUAN Wen-Jun SONG Chong-Lin ZHANG Qing-Mao LV Gang 6 （State Key Laboratory of Engine, Tianjin 300072 ） 0 0 Abstract ： The purifying performance of particulate oxidation catalyst (POC) with the coating of . La Ce Mn Bi 0 is studied under the real diesel engine exhaust on the engine bench. The removal rate of HC 1 0.8 0.2 0.7 0.3 3 1 and CO reaches more than 90% with simultaneous utilization of POC and commercial DOC. While the removal rate 7 of the particulate matters (PM) increases with the increment of the catalyst loading. Under the condition of 2510 1 0 r/min and 100% load, the purification efficiency of PM using POC 20 is 89.8%, among which 38.7% can be contributed to oxidation process. It is indicated that the catalyst of La Ce Mn Bi 0 has an excellent 2 0.8 0.2