degradation英文学习资料 .pptxVIP

;PSSA membrane;Hao J, Jiang Y, Gao X, et al. Degradation reduction of polybenzimidazole membrane blended with CeO2 as a regenerative free radical scavenger[J]. Journal of Membrane Science, 2017, 522:23-30.;Fuel cell effluent water was analyzed to measure the fluoride emission rate(FER), which is used as a quantitative indicator of the membrane degradation rate, analyzed using an ion selective electrode. The membranes were tested in standard cells at 90℃, 30% RH, H2 and O2 as reactants at open-circuit condition. Membrane thickness; reactant concentration.;此为上文的详细版本;Proton conductivity of Nafion/SnO2/SnO2-SO3H nanocomposite membrane is slightly lower than that of pure Nafion but higher than un-sulfonated Nafion/SnO2. The Fenton test results indicate that the fluoride release and weight loss of Nafion/SnO2/SnO2-SO3H are less than those in the pure Nafion membrane, and further confirmed by ATR-FTIR and SEM.;1. Alkali and alkaline earth metal ions do not have any specific effects on membrane degradation. 2. Fe2+ and Cu2+ significantly enhance the decomposition rate of Nafion due to the formation of strongly nucleophilic radicals upon H2O2 at these catalyst ions. 3. Both main chain and the side chains are decomposed at similar rates by radicals attack(decomposition of F and –SO3H, FTIR and solid state 19F NMR). ;RIG PEM Fenton reagent SEM cross section and surface XPS C1s O1s F S FTIR