核磁共振波谱分析-8.pptVIP

常见有机化合物的固体15N CP/MAS NMR谱 Chemical Shift (ppm) Structure Chemical Assignment NO3- = 0 NH4+= 0 30 to 0 410 to 380 ?-N=O Nitroso- 25 to -25 405 to 355 NO3- or NO2- Nitrate or Nitrite -20 360 CH3NO2 Nitromethane (solution NMR) -10 to -30 350 to 330 - Oxime(s) -25 to -90 355 to 290 Hydroxyimine, Phenazine Pyridine (-80 ppm) , Nitrile (Knicker) -90 to -150 290 to 240 N7 of Purines -120 to -140 260 to 240 Pyroxime(s) -150 to -180 230 to 200 Nitrile (Steelink) -220 to -270 160 to 110 -O=C-NH-OH Pyrrole, Carbamate N-C=O- Amide(s), Lactam(s) -230 to -240 150 to 140 -NH-CO-CH3 Chitin Structure