论文--电镀光亮镍钛合金工艺的研究.docVIP

PAGE PAGE 9 电镀光亮镍钛合金工艺的研究 摘要： 本文介绍了一种在含有主、辅配位剂的水溶液中电镀光亮NiTi合金的工艺。运用Hull Cell, 小槽电镀，电化学测试，以及扫描电子显微镜和X-射线衍射等方法，研究了Ni2+、Ti2+在溶液中的电沉积时的行为和合金沉积层的结构 。结果表明，在含有特殊的配位剂的水溶液中，Ti借助于Ni的“诱导”作用，可以以合金的形式在阴极上电沉积出来；所得的NiTi合金层光亮，均匀，含Ti在10%～35%之间，其为层状的均匀的晶态结构。而且，合金层中的含Ti量与溶液中Ti盐的浓度成正比，与阴极电流密度成反比。在5% NaCl溶液中的实验还表明，NiTi合金层比Ni层耐蚀能力高于40%。其可作为Ni,Cr或Ni＋Cr的替代镀层。此外，研究的镀液使用的pH、温度、电流密度范围宽；阴极电流效率在50%～70%，且随pH、温度的上升而增加，随电流密度的上升而下降。推荐的电镀光亮Ni-Ti合金溶液组成及操作条件是：NiSO4.6H2O, 50～60g/L, NiCl2.6H2O 0～15g/L, Ti盐液 50～125ml/L, H3BO3 35～40g/L，Na3C6H5O7˙2H2O 50～60g/L, JC-An 10～15 g/L, 光亮剂 2～4 ml/L, 辅助剂 8～10 ml/L, pH : 3.5～5, 温度: 40～60℃, 阴极电流密度 ：1.0～5.0A?dm-2, 阳极: 镍板，或不锈钢板，或钌钛合金阳极. 关键词：电镀；电镀镍钛合金；配位剂；光亮剂；电化学行为测试 Research on Bright Nickel-Titanium Alloy Electroplating Process HU Zhe1, ZUO Zhengzhong2*, YANG Juan1 , LI Yuliang1 , SONG Wenchao 1 (1,Wuhan Jadechem Chemicals ( J C ) Co. Ltd ., Wuhan, Hubei 430023， 2,College of Chem. Molecular siences, Wuhan Univ., Wuhan,Hubei 430072,) Abstract：This paper introduced a novel process for Nickel-Titanium alloy electroplating, which was carried in aqueous solution containing both major/auxiliary complexing agent. Hull cell, small cell, electrochemistry test, Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) etc. methods were conducted, to investigate the electro-deposition behaviors of Ni2+、Ti2+ in solution and the structure of alloy deposits. The results indicated that Ti can be electro-deposited on cathode in the form of Ni-Ti alloys in special complexing agents containing aqueous solution, with the aid of “induction effects” by Ni; the resulting Ni-Ti alloy layer was bright, smooth, with 10%~35% of Ti in mass, displaying homogenous laminated crystal structure. The percentage of Ti in alloy plating layer was proportional to the concentration of Ti-salt, and was inversely proportional to current density in cathode. Experiments in 5% NaCl solution suggested that Ni-Ti alloy plating layer was 40%