喷雾热解法在硅衬底上生长定向碳纳米管阵列.pdf

第28卷摇 第4期 新摇 型摇 炭摇 材摇 料 Vol.28摇 No.4 摇 2013年8月 NEW CARBON MATERIALS Aug. 2013 摇 文章编号:摇 1007鄄8827(2013)04鄄0284鄄05 喷雾热解法在硅衬底上生长定向碳纳米管阵列 1 2 3 3 V SAngulakshmi ,摇 K Rajasekar ,摇 C Sathiskumar ,摇 S Karthikeyan (1. Department of Chemistry,Kathir college of Engineering,Coimbatore,TN,India; 2. Department of Nanotechnology,Anna University of Technology,Coimbatore,TN,India; 3. Department of Chemistry,Chikkanna Govt. ArtsCollege,Tirupur,TN,India) 摘摇 要:摇 以向日葵油的甲基酯为碳源,二茂铁为催化剂前驱体,Ar为载气,通过喷雾热解法在硅衬底上合成定向碳纳米管阵 列。 结果表明,在硅衬底上原位形成Fe催化剂纳米颗粒。 由拉曼光谱、透射电镜图和X鄄射线衍射谱图显示所制定向碳纳米 管阵列具有较好的石墨化程度,其直径为10~30nm,管壁约为10nm。 所制定向碳纳米管阵列中残留的催化剂含量可以忽 略。 关键词:摇 喷雾热解法;定向碳纳米官阵列;二茂铁;硅衬底;化学气相沉积 通讯作者:S Karthikeyan. E鄄mail:skmush@ Growth of vertically aligned carbon nanotubes on a silicon substrate by a spray pyrolysis method 1 2 3 3 V SAngulakshmi ,摇 K Rajasekar ,摇 C Sathiskumar ,摇 S Karthikeyan (1.Department of Chemistry,Kathir college of Engineering,Coimbatore,TN,India; 2.Department of Nanotechnology,Anna University of Technology,Coimbatore,TN,India; 3.Department of Chemistry,Chikkanna Govt. Arts College,Tirupur,TN,India) Abstract:摇 Verticallyalignedcarbonnanotubesona silicon substratewere synthesizedbya spraypyrolysismethodusingthemeth鄄 yl ester of Helianthus annuus oil asa carbon source,ferrocene asa catalyst precursor and argon asa carrier gas.