一维硫属化合物纳米材料的可控合成与相关NANO2fMEMS器件特性分析.pdfVIP

ABSTRACT This thesis includes two major parts. The first part systemically investigates the controllable synthesis, characterization, doping and alloying of one-dimensional nanomaterials of chalcogenides as well as the fabrication of related NANO devices. The second part is about the measurement, simulation and calculation of adhesion force/energy of the surface of polysilicon-based MEMS devices. The main achievements are as follows: 1. A hydrogen-assisted thermal evaporation method to synthesize the CdSe and CdS nanowire arrays was developed. The CdSe nanowire arrays homoepitaxially grew from the single crystal CdSe micro-rods, and the CdS nanowire arrays hetroeptiaxially grew on the single crystal CdSe miro-sheets. The products have excellent single-crystal nature and with highly order. Especially, the CdSe nanowire arrays on the CdSe microrods are recognized as a trunk-branch structure which can be utilized to explain its outstanding photoluminescence/laser properties. This new structure of CdSe is first reported by our group. Different shapes of PbS nanorod arrays were synthesized via hydrogen-assisted thermal evaporation approach. A self-catalyzed combined with a vapor-liquid-solid mechanism was provided to explain the shape evolution of PbS nanorod arrays. 2. Ternary CdSXSe1-X single-crystal nanoribbons with uniform and controllable compositions (0 ＜ x ＜1) were synthesized for the first time via sulfurization method. Photoluminescence measurements showed the CdSxSe1-x NRs to have tunable near-bandgap sharp emission and lasing action from 542 nm to 668 nm. 3. High quality Cd0.9Mn0.1S nanobelts have been synthesized using a one-step thermal evaporation method in large scale. The room-temperature photoluminescence spectrum of Cd0.9Mn0.1S nanobelts fe