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22 1 No.1 Vol.22
2008 2 Journal of Chemical Engineering of Chinese Universities Feb. 2008
1003-9015(2008)01-0071-06
,
( , 113001)
TiO ⋅xH O TiO
2 2 2
N -Hammett NH -TPD-FT-IRXRD LRS WO 15% (wt)
2 3 3
TiO2 TiO2
TiO2 WO3 WO3
15 %(wt)500 WO WO
3 3
L B L B TiO
2
O643.361 TQ426.82 A
Studies on Tungsten Oxide Modified Titania Solid Superacid Catalysts
REN Li-guo, ZHANG Xiao-li
(Department of Materials Science Engineering, Liaoning University of Petroleum Chemical Technology,
Fushun 113001, China)
Abstract: Tungsten oxide modified titania solid superacid catalysts were prepared by impregnation of
TiO ·xH O powder in ammonium metatungstate aqueous solution and calcination in air with high temperature.
2 2
The modified catalysts prepared were characterized by NH3-TPD, FT-IR of pyridine adsorption, XRD and LRS.
The results show that the small amount addition of tungsten oxide can remarkably increase the acidity and the
acid strength of the modified catalysts prepared, both the Lewis and Bronsted acid sites exist on the surface of
the modified catalysts and these two species of acid sites are i
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