用麦芽糊精制备聚羧酸系减水剂-硅酸盐学报.pdf

第 45 卷第 11 期 硅 酸 盐 学 报 Vol. 45 ，No. 11 2 0 1 7 年 1 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY November ，2017 DOI ：10.14062/j.issn.0454-5648.2017.11.14 用麦芽糊精制备聚羧酸系减水剂 吴井志，乔 敏，高南箫，吕志锋，陈 健，于 诚，冉千平 (江苏苏博特新材料股份有限公司，高性能土木工程材料国家重点实验室，南京 211103) 摘 要：以麦芽糊精为原料，经过醚化改性和羧基化改性后，制备了一种聚羧酸系减水剂(PCWR) 。通过红外光谱、核磁共 振、X 射线衍射和扫描电镜测试表征了其分子结构和形态，证明 PCWR 已成功引入羟丙基基团和羧基基团。测定了 PCWR 的取代度、吸附性能、水泥浆体流变行为以及水泥净浆和混凝土性能，并在此基础上分析了其增稠和减水的作用机理。结果 表明：PCWR 的醚化取代度越大，增稠效果越好，而酯化取代度越大，其在水泥颗粒表面的吸附量越大，对水泥浆体的分散 性越好；与普通萘系减水剂相比，PCWR 的减水效果更好，并且能更好地改善混凝土状态。 关键词：麦芽糊精；醚化；羧基化；流变；减水剂 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2017)11–1658–07 网络出版时间：2017–10–09 13:56:00 网络出版地址：/kcms/detail/11.2310.TQ1356.006.html Preparation of Polycarboxylate Superplasticizer Water-Reducing Agent Using Maltodextrin WU Jingzhi, QIAO Min, GAO Nanxiao, LÜ Zhifeng , CHEN Jian, YU Cheng, RAN Qianping (State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China) Abstract: A polycarboxylate superplasticizer water-reducing agent (PCWR) was prepared via etherification and carboxylation with maltodextrin as a raw material. The molecular structure and morphology were characterized by Fourier transform infrared spectroscopy (IR), nuclear magnetic resonance (NMR), X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The degree of substitution (Ds) of PCWR, adsorption performance, rheological behavior of cement paste, cement paste and concrete performance were measured, and the corresponding mechanism was analyzed. The results show that a greater DS of etherification has a better thickening