氧化硅基底负载TiO2薄膜的制备及其光催化应用研究.docxVIP

氧化硅基底负载Ti02薄膜的制备及其 光催化应用研究 贺育敢朱美英龙昊杨俊佼 北京化工大学理学院 摘要： 以钛酸丁酯为钛源，乙酰丙酮和冰醋酸为水解抑制剂，聚乙二醇为致孔剂，制 备了一种稳定的TiO,水溶胶。采用浸渍提拉法将TiO?溶胶负载到活化的载玻片 上，再经180°C水热或500°C?烧得到Ti02薄膜催化剂。采用扫描电子显微镜 (SEM)、原子力显微镜(AFM)、透射电子显微镜(TEM)、X射线晶体衍射(XRD) 和Rmnan光谱等分析手段对样品进行了表征，结果表明:TiO?薄膜是由粒径为於2 mn的球形颗粒组成的多孔结构，其晶型为结晶度良好的锐钛矿。以甲基橙为光 降解物，在紫外灯下测试薄膜的光催化性能，结果显示锻烧处理的TiO?薄膜催 化剂的光催化活性优于水热处理，对低浓度甲基橙的降解效率达90%以上，并 且多次重复使用后光催化活性基木保持不变。 关键词： Ti02薄膜;光催化;溶胶-凝胶法; 作者简介：贺育敢男，1990年生，硕士生 作者简介：杨俊佼 E-nia订:yangj j@mail. buct. edu. cn 收稿日期：2017-03-27 Fabrication of Ti02 films coated on a Si02 substra/te and their application in photocatalysis HE YuGan ZHU MeiYing LONG Hao YANG JunJiao Faculty ofScience, Beijing University of Chemical Technology; Abstract： A very st able Ti02 hydrosol has been prepared via a facile sol-gel process using titanium butoxide and polyethylene glycol ( PEG) as a precursor and porogen respectively in the presence of acetylacetone and acetic acid. The TiO2 hydrosol was coa ted on a SiO2 substrate by a dip-coating met hod. Highly homogenous and transparcnt Ti02 films were fabricated by cither a hydrothermal process at 180 °C or by calcination in the air at 500 °C. The films were characterized by XRD, Raman spectroscopy, SEM, TEM and AFM. The results showed that TiO2 films were the anatase phase, firmly coated on the SiO2 substrate, and mainly made up of nanoparticles with size in the range 8 ~ 12 nm. The photocatalytic degradation of methyl orange ( MO) in aqueous solution was carried out in order to evaluate the photocatalytic activity of the films. The results showed that the photocatalytic performanee of TiO2 films prepared by armealing was better than those prepared by a hydrothermal process. The degradation ratio of MO under UV light irradiation reached 90% and did not changc significantly when the catalyst was reused several times. Keyword： Ti02 f订m; photocatalysis; sol-gel method; Received： 2017-03-27 引言 Ti O2光催化剂由于具有性质稳定、价廉、无毒、无污染等优点而在光催化领域 得到广泛应用，如光催化储能、光催化降解有机污染物以及光催化杀菌等等，特 别是在光催化降解有机污染物方面的应用一直以来备受科