添加剂pvppeg对pvdf省略gdmac铸膜液扩散性质的影响杨晓天.pdfVIP

21 2 No.2 Vol.21 2007 4 Journal of Chemical Engineering of Chinese Universities Apr . 2007 1003-9015(2007)02-0221-06 PVPPEG PVDF/PVP(PEG)/DMAc , , ( , 200237) (PVP)(PEG) (PVDF)/ PVP(PEG)/(DMAc)PVP PEG PVDF 52.52×10−6 g⋅s− 1/25 PVP PEG20000 17.11 22.53×10−6 g⋅s− 1/2 PVPPEG PVDF TQ028.8 O645.14 A Effect of Polymer Additives PVP and PEG on the Diffusion Property of PVDF/PVP(PEG)/DMAc Dope Solution YANG Xiao-tian, XU Zhen-liang, WEI Yong-ming (Membrane Science and Engineering Research Development Center, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China) Abstract: Immersion precipitation phase inverse method and light transmission test were combined to investigate the effect of polymer additives, PVP and PEG, on the diffusion property of PVDF/Additives/DMAc dope solution. The concentration of PVP and molecular weight of PEG were changed in the experiment. The results revealed that the outflow of solvent during the initial stage of membrane formation was controlled by the −6 − 1/2 Fickian diffusion. The apparent diffusion coefficient of solvent is 52.52×10 g⋅s when no additive is added. −6 − 1/2 The coefficient changes to 17.11 or 22.53×10 g⋅s respectively when 5% PVP or PEG 20000 is added. Both PVP and PEG decrease the outflow of solvent. Meanwhile non-solvent inflow increases as indicated by light transmission test. The experiments reveal that solvent outflow is controlled by the system’s viscosity while non-solvent inflow is controlle