锂离子电池的碳导电添加剂.ppt

CIBF2005, April 3rd, 2005 Electrical performance of carbon black碳黑的导电表现 Carbon blacks with higher structure show percolation threshold at lower carbon content高结构碳黑的渗透值较低 The higher the OAN is the less carbon black is needed for a given resitivity level of the electrode达到同样的导电值吸油值大的碳黑需要量小 CIBF2005, April 3rd, 2005 Electrical performance of carbon black碳黑的导电表现 0 50 100 150 200 250 300 350 400 0 200 400 600 800 1000 Structure结构(DBP absorption) Specific surface area 比表面积 (m2/g) MMM Process/MMM法 Furnace Process炉黑 Thermal Process热黑 Acetylene Black乙炔黑 Gaseification Process气化法 Channel Process/槽黑 Aftertreated furnace Lamp Process灯黑 CIBF2005, April 3rd, 2005 Problems associated with highly structured carbon black高结构碳黑的问题 High polymer binder absorption decreases mechanical electrode stability 吸收更多的粘合剂会降低电极的机械稳定性 High electrolyte absorption could lead to strong swelling of the electrode 高电解液的吸收会导致电极的膨胀 High viscosity of the electrode slurry/higher demand of solvent 电极的高粘度需要更多的溶剂 High surface area leads to chemical and electrochemical side reactions especially in the charged state of the electrodes 高比表面积会导致化学和电化学的副反应.特别是在充电状态 Higher specific charge losses in the negative electrode related to SEI formation due to increased electrode area 在负极中的更高的比电荷损失.这是由于表面积增加导致SEI的形成 Higher electrolyte oxidation rate at the charged positive electrode 正极充电时的电解液高氧化率 Higher dissolution rate of manganese in the electrolyte in the case of a LiMn2O4 spinel positive electodes 尖晶石电极下,在电解液中的Mn的高溶解 Effects depend on the carbon concentration and might be negligible 这些效应取决于碳黑浓度,也可能被忽略. Process-related issues加工: Issues related to the battery performance和电池性能有关的几个问题 CIBF2005, April 3rd, 2005 Structure degradation by high shear energy高剪切下的结构降低 Absorption stiffness changes in an intensive mixer 在强搅拌下的吸收硬度 0.0 0.5 1.0 1.5 2.0 0 5 10 15 20 25 30 35 Absorption stiff ness吸收硬度 [mL/5 g] Treatment time处理时间 ENSACO TM 260 Knapsack Super TM S Super TM P Denka CIBF2005,