高耐候聚硅氧烷涂料地研究开发.pdfVIP

第二届全国涂料科学与技术会议论文集 中国．上海 高耐候聚硅氧烷涂料的研究开发 商树学武翻民 复旦大学材料科学系，国家教育部先进涂料工程研究中心，上海200433 摘要：本文以自制的高硅含量、高固低粘的改性聚硅氧烷树脂为基础，制备了聚硅氧烷涂料，并用 氨基硅烷固化，得到了抗冲击性、附着力具佳的聚硅氧烷涂层。考察了固化剂用量和种类对聚硅氧 烷涂层老化失光和变色行为的影响规律，并与聚氨酯涂料、国际油漆聚硅氧烷涂料进行了耐老化和 耐盐雾性能比较。研究表明，聚硅氧烷涂料的耐老化性除了改性聚氧烷树脂外，还可通过固化剂的 种类和用量来进行调节。聚硅氧烷涂料具有远优于聚氨酯涂料的耐老化性能和耐盐雾性，可作为氟 碳面漆的理想替代品。 关键词：聚硅氧烷、高耐候、面漆、氨基硅烷 of withExcellent DevelopmentPolysiloxaneCoatings Long-termDurability Shuxue Wu Zhou，Limin ofMaterials ResearchCenterof of Educationof (Department Science，AdvancedCoatings Ministry China, Fudan University,Shanghai200433，China) Abstract：Modifiedresinswith silicon solidandlow were polysiloxane high content，high viscosity inour were withthese modified resins developedlab．Polysiloxanepigmentcoatingsprepared polysiloxane silane asa obtained exhibit usingamino—containingcoupleagentscuringagent．The coatings excellent resistanceand adhesiveforce．Effectsofthe and of onthe impact good type dosagecuringagents gloss reductionand ofthe accelerated color testswere change coatingsduring weathering investigated．The the andcorrosion the self-made performances，especiallyweatherability resistance(insalt-fogtests)of were withthatofthecommercialIP and pol