a nanocomposite of moo3 coated with ppy as an anode material for aqueous sodium rechargeable batteries with excellent electrochemical performance一种纳米moo3包覆聚吡咯电化学性能优良的水钠离子充电电池的负极材料.pdf

Electrochimica Acta 116 (2014) 512–517 Contents lists available at ScienceDirect Electrochimica Acta j o u r n a l h o m e p a g e: w w w. elsev /locate/elec t a c ta A nanocomposite of MoO3 coated with PPy as an anode material for aqueous sodium rechargeable batteries with excellent electrochemical performance Y. Liu a,b , B.H. Zhang a,b , S.Y. Xiao a , L.L. Liu a , Z.B. Wen b,∗ , Y.P. Wu a,∗ a New Energy and Materials Laboratory (NEML), Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China b College of Chemistry and Chemical Engineer, Jiangxi Normal University, Nanchang 330022, China a r t i c l e i n f o a b s t r a c t Article history: A nanocomposite of molybdenum trioxide (MoO3 ) nanobelts coated with polypyrrole was prepared as an Received 12 August 2013 anode material for aqueous rechargeable sodium batteries (ARSBs). When nanowire Na0.35 MnO2 is used Received in revised form 23 October 2013 −1 −1 as the cathode, the ARSB can deliver an energy density of 20 Wh kg at 80 W kg and even maintain 18 Accepted 14 November 2013 Wh kg−1 at 2.6 kW kg−1 in 0.5 mol L−1 Na SO aqueous electrolyte, suggesting a good rate capability that 2 4 Available online 26 November 2013