异化MnIV还原菌激活及其对有机药物去除-中国环境科学.PDFVIP

中国环境科学 2019,39(1) ：298~305 China Environmental Science 异化 Mn(IV)还原菌激活及其对有机药物去除 翟 俊 1*,王 熔 1,黄泽金 2,王泉峰 1,刘文博 1,陈怡璇 1 (1.重庆大学城市建设与环境工程学院,重庆 400044 ；2. 中国市 政工程西北设计研究院有限公司陕西分院,陕西 西安 710075) 摘要： 以嘉陵江沉积物为菌源,利用荧光绝对定量(qPCR)技术探究了不同碳源(葡萄糖和乙酸钠)和不同形态的锰氧化物(δ-MnO2 和锰矿粉)对异化 Mn(IV)还原菌激活效果的影响.在此基础上,研究了激活效果最佳的异化 Mn(IV)还原菌对卡马西平、布洛芬、萘普生、雌激素和双氯芬酸 5 种有机药 物的去除效果.结果表明,葡萄糖作为碳源,δ-MnO2 作为电子受体时激活效果最佳,Mn2+ 10d 累计生成浓度达 416.03mg/L,TOC 消耗率达 88.24%.激活后的 异化金属还原菌在有无外加碳源时对卡马西平和布洛芬均无明显去除,对萘普生在外加碳源时能实现 11.88%的去除.雌二醇和双氯芬酸可以作为异化 Mn(IV)还原菌唯一碳源,其去除率可达 75.70%和 58.25%. 关键词：异化 Mn(IV)还原；有机药物；生物去除；qPCR 中图分类号：X172 文献标识码：A 文章编号：1000-6923(2019)01-0298-08 1* Activation of dissimilatory Mn(IV) reducing bacteria and their removal of typical pharmaceuticals. ZHAI Jun , WANG 1 2 1 1 1 Rong , HUANG Ze-jin , WANG Quan-feng , LIU Wen-bo , CHEN Yi-xuan (1.College of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400044, China ；2.China State Construction Engineering Corporation AECOM Consultants Co., Ltd Shaanxi Branch, Xian 710075, China). China Environmental Science, 2019,39(1) ：298~305 Abstract ：In this study, sediment from JiaLing River was cultivated as inoculum of dissimilatory Mn(IV)-reducing bacteria. By using qPCR technique, this study investigated the effects of different carbon sources (glucose and Na-acetate) and different forms of manganese oxides (δ-MnO2 and manganese ore powders) on activating dissimilatory Mn(IV)-reducing bacteria. Moreover, the most active dissimilatory Mn(IV) reducing bacteria was further tested the