沸石加气混凝土生物填料制备及其序批式脱氮水处理.pdf

中国环境科学 2017,37(6) ：2150~2159 China Environmental Science 沸石加气混凝土生物填料制备及其序批式脱氮水处理 * 边 佳,陈天虎 ,鲍 腾,程 鹏,陈 冬,庆承松 (合肥工业大学资源与环境工程学院,安徽 合肥 230009) 摘要：以天然斜发沸石粉为主要原料,水泥为粘结剂,铝粉为造孔剂通过优化实验制备出沸石加气混凝土生物填料(ZPBF),并利用偏光显微 镜(PM)、扫描电子显微镜(SEM)等技术来表征 ZPBF 孔结构特征.结果表明:ZPBF 开放孔隙率达到 29.55%,为微生物进入 ZPBF 的内部附着 2 生长提供空间.BET-N2 吸附测得介孔孔径平均 11.92nm,比表面积 59.54m /g,有利于离子交换吸附.ZPBF 装填实验柱挂膜成熟后, 以模拟含 NH4+-N 废水进行离子交换吸附、排空、鼓风微生物硝化再生、淋洗硝酸盐四阶段序批式运行,当离子交换吸附阶段 HRT 为 2.8h,进水 NH4+-N 浓度 10mg/L,以出水NH4+-N 浓度 1.5mg/L 为穿透点,可吸附 NH4+-N 运行 5d,鼓风 24h 可完成再生,NH4+-N 平均去除率达到 87%,TN 平均去除率达到 60%, 出水达到北京城镇污水处理厂水污染物排放标准一级 B. 关键词：加气混凝土填料；脱氮；序批式水处理；生物再生 中图分类号：X703,X783.4 文献标识码：A 文章编号：1000-6923(2017)06-2150-10 Development and characterization of zeolite biological porous filter for denitrification wastewater treatment by * intermittent operation. BIAN Jia, CHEN Tian-hu , BAO Teng, CHENG Peng, CHEN Dong, QING Cheng-song (School of Resource and Environmental Engineering, Hefei University of Technology, Hefei 230009, China). China Environmental Science, 2017,37(6)：2150~2159 Abstract ：Zeolite porous biological filter (ZPBF) was prepared using mixed cement, raw zeolite, and aluminum powder through optimization experiment and used as a novel filter medium in biological aerated filter (BAF). The properties of the ZPBF were analyzed by scanning electron microscopy (SEM), and porosimetry. The results show that ZPBF has a large BET-N 2 2 (59.54m /g) and average pore diameter (11.92nm) as well as a high porosity (29.55%). In addition, the uniform and interconnected pores in ZPBF made it suitable for the microbial growth. In order to prove the feasibility of