nature杂志二维硼纳米片的实验法实现.pptxVIP

二维硼纳米片的实验法实现;Contents;Abstract;Density functional theory：; B 12 icosahedral cages VS graphite ; boron clusters VS carbon clusters ; . Boron has the same short covalent radius and the flexibility to adopt sp 2 hybridization as carbon, which would favour the formation of various low-dimensional allotropes.; particularly interesting; Dirac fermions;Theoretical prediction VS experimental realization;Growth of 2D boron;Growth of 2D boron;图注：;bias voltages：; The β12 sheet was placed on Ag(111) with the boron rows in the [ - 112] direction of the Ag(111) surface, as shown in Fig. 2a.a,b, Top and side views of the S1 modelc, Simulated STM topographic image of the β 12 sheet. ;d,e, Top and side views of the S2 model, which corresponds to a χ 3 sheet of 2D boron on Ag(111). f, Simulated STM topographic image of the χ 3 sheet. Models of the β 12 and χ 3 sheets are superimposed on their simulated STM images, which agree very well with the experiments. The striped pattern of S1 and the alternating bright–dark protrusions of S2 are both reproduced well.; first-principles calculations; lattice mismatch; Moiré pattern;Reason for 2 different phases;Measuring the atomic density of boron ;1、 By counting the area ratio of the S1 phase on Ag(111) in the STM images, the atomic density of boron in phase S1 was obtained. We performed experiments on samples with different boron coverages, and the calibrated atomic density of boron in the S1 phase wasfound to be 33.6± 2.0 nm ?2 , identical to that calculated using theβ 12 sheet model (34.48 nm ?2 ), within a small range of error. 2、 when we annealed the S1 surface and turned it into the S2 phase, we did not observe a significant change in the total area of the islands, indicating that the boron densities in the two structures are approximately the same. This is consistent with the fact that the χ 3 sheet model has a similar boron density (31.3 nm ?2 ) as the β 12 sheet. The above experimental facts confirm the valid