工业废水中非金属离子磷和氰含量的快速测定法研究.docVIP

范文最新推荐 PAGE1 / NUMPAGES1 工业废水中非金属离子磷和氰含量的快速测定法研究 摘要：本课题分别利用钼酸铵分光光度法测定样品中微量磷和异烟酸mdash;吡唑啉酮分光光度法测定样品中氰化物含量。异烟酸mdash;吡唑啉酮分光光度法测定样品中氰化物含量，在40℃的条件下（可用水浴控制），在分光光度计上于646nm波长处，用蒸馏水作参比，用1cm比色皿进行测定，记录吸光度。钼酸铵分光光度法测定样品中微量磷，用1cm比色皿于710nm波长处，以蒸馏水为参比，测量吸光度。最后分别利用稳定的指示剂寻找模拟试剂。制作标准溶液作为参比，制备模拟试剂，实现用目视比色法测定样品中微量磷和氰化物含量。解决中小型企业在缺乏仪器（分光光度计）的情况下，自行测定废水中微量磷和氰化物含量是否达到国家排放标准。 关键词：磷；氰；钼酸铵；异烟酸mdash;吡唑啉酮；分光光度法；模拟试剂 Fast test of the amount of Non-metallic Ions mdash;mdash;Phosphorus and Cyanide in Industrial Wastewater Abstract: In this topic,the microscale phosphorus ofsample is determined by ammonium molybdate spectrophotometry and cyanide in the sample is determined by Isonicotinic acid-pyrazolone spectrophotometry. In the Isonicotinic acid-pyrazolone spectrophotometry determining the microscale phosphorus ofsample, a spectrophotometer is used at 646 nm wavelength to measure the absorbance under the conditions of 40deg;C controlled by water bath, using 1cm cuvette and distilled water as reference. In the ammonium molybdate spectrophotometry, a Spectrophotometer is used at 710 nm wavelength to measure the absorbance under the conditions of using 1cm cuvette and distilled water as reference. At last , indicators which are stable are respectively used to compound the simulation of reagents.Making standard solution as reference and preparing the simulation of reagents makes it possible that content ofand cyanide in the sample can be measured with visual colorimetry. That helps some small and medium-sized enterprises which is lack of equipment(spectrophotometer) determine by themselves whether the content of phosphorus and cyanide in the waste water meets the national emission standards. 3.1.12 标准工作曲线的建立16 3.1.13 配制相应的模拟试剂1代替标准溶液系列16 3.1.14 模拟试剂1在长时间内的稳定性试验 17 3.1.15 水样的测定 18 3.1.16 实验数据偏差 19 3.1.17 准确度实验 19 3.2 磷含量分析20 3.2.1 标准溶液吸收光谱曲线20 3.2.2 钼酸盐加入量确定20 3.2.3 抗坏血酸加入量确定21 3.2.4 显色时间与吸光度的关系21 3.2.5 溶液的稳定性实验22 3.2.6 尝试寻找模拟试剂2 22 3.2.7 模拟试剂2最大吸收波长的确定22 3.2.8 茜素红溶液颜色与溶液PH的关 23 3.2.9 模拟试剂2吸