生物质焦与煤共气化特性研究李啸颖1王静松1陈瑞泷2李聪1薛庆国.doc

生物质焦与煤共气化特性研究 李啸颖1 王静松1 陈瑞泷2 李聪1 薛庆国1 （1,北京科技大学钢铁冶金新技术国家重点实验室，北京100083;2,江苏大学冶金工程系，镇江市） 摘要：本文利用非等温热重分析法研究了生物质焦与煤的共气化特性，探讨了生物质焦与煤共气化反应特征温度的变化情况，并分别运用Doyle和Coats-Redfern近似函数计算了反应动力学参数。采用Doyle法计算时，相关系数R2值比Coats-Redfern法更大，因此Doyle法计算结果更合理。采用Doyle法计算出：生物质焦的气化反应活化能为134.97 KJ·mol-1，烟煤和无烟煤分别是197.85 KJ·mol-1和171.36 KJ·mol-1。随着无烟煤、烟煤中生物质焦掺混的比例增加，反应活化能不断下降。研究可得生物质焦可以促进两种煤的气化反应，降低煤的最终反应温度和气化反应活化能。 关键词：生物质焦，煤，共气化，活化能 Study on the characteristics of co-gasification of coals and biomass char Xiaoying Li1 Jingsong Wang1 Ruilong Chen2 Cong Li1 Qingguo Xue1 （1,State Key Laboratory of Advanced Metallurgy, University of Science and Technology of Beijing，Beijing100083;2,Department of Metallurgy in Jiangsu University,Zhenjiang212013） Abstract: In this paper, co-gasification reaction of biomass char and coals were studied by non-isothermal thermo gravimetric analysis. The change of the characteristic temperature of co-gasification reaction was investigated, while Doyle and Coats-Redfern approximate functions could be used to simulate kinetics parameters of the reaction. The data calculated by using Doyle method hold a higher value of R2 than the Coats-Redfern method, so in this study the Doyle method is more reasonable. In Doyle method , the apparent activation energy of the biomass char used in this study is about 134.97 KJ·mol-1,while the bituminite is 197.85 KJ·mol-1 and the anthracite is 171.36 KJ·mol-1.And as the weight rate of biomass char added in coals become larger the apparent activation energy become smaller. It was concluded that biomass char can make a promote role in coals’ gasification process through lowing the final reaction temperature and the apparent activation energy. Key words: biomass char; coal; co-gasification; the apparent activation energy 目前，化石能源短缺的问题已经逐渐成为阻碍冶金行业发展的主要问题之一。生物质作为一种新型绿色能源在各个领域的应用受到广泛关注[1]。生物质是可再生碳资源，同时具有资源丰富，环境友好等特点，拥有较好的利用前景[2-4]。生物质因其挥发份含量较高，若直接用作还原剂损耗太大，故先将其炭化制生物质焦[5]。针对目前冶金领域对于生物质焦的研究较少、基础研究数据缺乏的现状，本文利用非等温热重分析法对烟煤、无烟煤和生物质焦的二氧化碳气化反应特性以及