负温防冻剂混凝土的界面显微结构与性能-硅酸盐学报.pdf

第35 卷第8 期 余其俊等：水泥、粉煤灰及其硬化体中Cr(Ⅵ)溶出条件与其影响因素 · 1125 · 第35 卷第8 期 硅 酸 盐 学 报 Vol. 35 ，No. 8 2 0 0 7 年 8 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY August ，2007 负温防冻剂混凝土的界面显微结构与性能 杨英姿，巴恒静 (哈尔滨工业大学材料科学与工程学院，哈尔滨 150001) 摘 要：研究了不同种类的防冻剂、矿物掺合料对正、负温下水泥净浆、砂浆及混凝土力学性能的影响。通过对比实验表明：水泥净浆、砂浆及混凝 土在正、负温条件下抗压强度的变化规律存在显著差异，这取决于其内部显微结构，尤其是界面显微结构的差异。利用显微硬度计、扫描电镜、能谱 分析、X 射线衍射研究了防冻剂混凝土界面过渡区的范围、元素分布、钙硅比及氢氧化钙的取向度。结果表明：防冻剂能够改善负温下混凝土的界面 显微结构，防冻剂和矿物掺合料的复合使用可为负温混凝土提供理想的界面显微结构。 关键词：负温混凝土；界面显微结构；外加剂 中图分类号：TU528 文献标识码：A 文章编号：0454–5648(2007)08–1125–06 INTERFACE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF CONCRETE WITH ANTIFREEZING ADMIXTURE AT SUBZERO TEMPERATURES YANG Yingzi，BA Hengjing (School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001, China) Abstract: The mechanical properties of hardened cement paste, mortar and concrete with different antifreezing admixture and min- eral admixture cured at 20 ℃ and –20 ℃ were investigated. The distinct difference on the compressive strength changes of hardened cement paste, mortar and concrete maybe attributed to the bigger difference within the interface transition zone (ITZ). Micro-hardness test, scanning electron microscopy, energy dispersive X-ray analysis and X-ray diffraction were used to analyze the range of the ITZ, element distribution, calcium oxide/silica ratio and orientation of calcium hydroxide. The results show that the anti-freezing admix- ture can improve the ITZ microstructure in concrete at sub-zero temperatures. Antifreezing admixture combined with mineral admix- ture can provide an ideal interface microstructure for concrete at sub-zero temperatures. Key words: concret