钼精矿真空冶炼过程中主要杂质元素分布的研究.docVIP

doi：10.3969/j.issn.1007-7545.2018. doi：10.3969/j.issn.1007-7545.2018.08.010 王磊，郭培民，孔令兵，赵沛，田志凌 (中国钢研科技集团有限公司 低温冶金与资源高效利用中心，北京 100081） 摘要：为提高钼精矿真空分解产品的质量，降低产品中Si、Ca、Mg、Al等杂质的含量，在冶炼过程中加入了碳粉。对钼精矿中主要杂质元素Si、Ca、Mg、Al在真空分解过程中的分布进行了研究。结果表明，在钼精矿中加入碳粉，有利于杂质SiO2、Al2O3、MgO、CaO的去除。在研究的温度范围内，硅脱除率~100%，镁脱除率~99.7%，铝脱除率~78.44%，随着碳含量的增加及时间的延长，其脱除率可能会进一步提高。钙脱除率~9.8%。采用品位为48%的低品位钼精矿为原料，在加入碳粉真空冶炼的条件下，得到的金属钼中钼含量达到了92%，S含量降至0.69%，主要杂质元素SiO2降至0.0021%，Cu0.005%，P0.005%，Mg降至0.001%，Al降至0.64%，Ca含量为0.51%。铁含量为4.44%，基本没有去除。 关键词：钼精矿；杂质元素；真空分解；金属钼产品 中图分类号：TF841.2 文献标志码：A 文章编号：1007-7545（2018）08-0000-00 Study on Impurity Behaviors in Vacuum Smelting Process of Molybdenite Concentrates WANG Lei, GUO Pei-min, KONG Ling-bing, ZHAO Pei, TIAN Zhi-ling (Center of Efficient Utilization of Resources by Low-temperature Metallurgy, China Iron Steel Research Institute Group, Beijing 100081, China) Abstract：Carbon powder was added in smelting process to improve quality of products in vacuum decomposition process and reduce impurity contents of Si, Ca, Mg, and Al in product. Distribution of main impurity elements of Si, Ca, Mg, and Al in molybdenite concentrates was studied. The results show that carbon addition into concentrates facilitates removal of impurities of SiO2, MgO, Al2O3, and CaO. Within the temperature range in the study, removal rate of Si is about 100%, removal rate of Mg is about 99.7%, and removal rate of Al is about 78.44%. Removal rate can be further improved with increase of carbon content and extension of time. The best removal rate of Ca is about 9.8%. With a low-grade molybdenite concentrate of 48% as raw material under the condition of vacuum smelting with carbon powder, Mo content in obtained product is about 92%, content of S drops to 0.69%, contents of main impurity element is SiO2 0.0021%, Cu0.005%, P0.005%, Mg 0.001%, Al 0.64%, and Fe 4.44%. Element of Fe is not removed at all. Key words：molybdenite concentrates; impurity element; vacuum decomposition; metal molybdenum 辉钼矿是自然界中最具有工业意