我国核能制氢技术研究进展.docVIP

我国核能制氢技术研究进展 张平，陈崧哲，王来军，徐景明 （清华大学 核能和新能源技术研究院，北京100084） 摘要: 氢作为清洁二次能源，有非常好的使用前景，以可持续的方式实现氢的大规模生产是实现氢的广泛利用的前提。核能制氢以来源丰富的水为原料，利用核能实现氢的高效、无温室气体排放的大规模生产；世界上许多国家，如美国、日本、法国、加拿大和中国，都在大力开展核能制氢技术的研发工作。从2005年起，清华大学开始展开核能制氢技术的研究，在2009年成功进行了对热化学碘硫循环和高温蒸汽电解的原理性工艺验证。2010年至今，在进行集成实验室规模的制氢台架（ILS）的开发及相关研究，将在2014年完成制氢能力100NL/h的ILS台架构建并实现连续稳定运行。本文介绍了清华大学关于核能制氢的研究规划，并对热化学碘硫循环的研究进展和主要结果进行了概述。 关 键 词: 氢能；核能制氢；热化学循环；进展 Development of Nuclear Production of Hydrogen in China ZHANG Ping，CHEN Songzhe, WANG Laijun, XU Jing-ming Institute of Nuclear and new energy technology (INET), Tsinghua University, Beijing 100084, China Abstract: Hydrogen is a promising clean secondary energy which needed to be produced from the primary energy. Nuclear hydrogen production, which generating hydrogen from water with nuclear energy, is considered as an efficient, greenhouse-free and massive hydrogen production. RD on the nuclear hydrogen production has been considerably conducted in many countries, including the United States, Japan, France, Canada, as well as in China. The researches was initiated in Tsinghua University since 2005, and the proof-of-concept experiments for the thermo-chemical iodine sulfur (IS) process and high temperature steam electrolysis (HTSE) were successfully carried out in 2009. Since 2010, the integrated lab scale facilities for the IS process and HTSE have been developed, the objective is to achieve the continuous stable operation of the two process with the hydrogen production rate of 100NL/h. In the paper, the RD plan of the nuclear hydrogen production program is presented, and the progress and the main results of the IS process is summarized. Key words: hydrogen energy; nuclear production of hydrogen; thermochemical cycle; progress 前言 传统化石燃料的有限储量和不可再生性以及其使用带来的温室效应等问题使清洁低碳能源研发受到重视。氢是无污染可再生的清洁能源，可储可输，在作为燃料和能源载体方面具有良好使用前景。此外，氢气在工业领域的使用需求不断增加。目前全世界氢气96%由化石燃料重整制备，排放大量CO2。要实现氢的大规模使用，必须发展安全、可持续、环境友好的制氢方式，核能制氢是解决氢气制备及引起的环境问题的最好解决方案之一。另外开发中的新能源由因其自身不稳定、分布不均衡、受环境和气候影响等特点，需要开发能源载体来实现其储存