测定氨氮的经验点滴.pdf

第 32 卷第 8期 环境科学与管理 Vol32 No8 2007 年 8 月 ENV IRO NM ENTAL SC IENCE AND M ANA GEM ENT Aug. 2007 文章编号 : 1673 - 1212 (2007) 08 - 0130 - 04 测定氨氮的经验点滴 朱智 , 张志贵 (克拉玛依市环境科研监测中心站 , 新疆 克拉玛依 834000) ( ) 摘 　要 :用纳氏比色法测定 NH - N 时 ,在保证斜率不变 b = 0. 0037 的条件下 ,减少显色剂中 HgC I - K I三分 3 2 之二的含量 ,聚乙烯醇做胶体稳定剂 ,显著提高了显色剂和显色的稳定度 ,并大大降低了空白吸光度 。以 KOH 和酒石酸钾纳做缓冲溶液 ,并增加 KOH 一倍的含量 ,保持恒定的显色碱度 , 同时也掩蔽了金属离子的干扰 。测 定废水 ,先做一条件试验 ,确定氨氮废水的稀释比 ,是测定氨氮的重要步骤 。 关键词 :聚乙烯醇 ; 缓冲溶液 ; 稀释比 中图分类号 : X830. 2 文献标识码 : A Imp rovem ent in D eterm in ing NH3 - N by H a sh ’s M ethod Zhu Zh i, Zhang Zh igu i ( Karam ay Mon itoring Center Station for Environm ental Science R esearch, Karam ay 834000 , Ch ina) A b stract: To m easure NH3 - N by N a sh ’s m ethod, under the condition of unchanged slop e (B = 0. 0037) , it wou ld have an obviou s increa se in the stab ility of co lor - develop ing reagent and co lor developm ent as well as a great decrea se in b lank ab sor bance to reduce by two th ird s of H gC I - K content in co lor - develop ing agent and u se po lyvinyl alcohol as co llo id stab ilizing a 2 gent. It wou ld m aintain a con stant color developm ent alkalin ity and also m a sk the interference of m etal ion to take KOH and pota s sium sodium tartrate a s buffer solu tion w ith a doub led KOH concentration. A lso, it is an important step to m ake a condition