以废治废——铝厂固废赤泥治理工业废气二氧化硫的应用研究.docxVIP

以废治废——铝厂固废赤泥治理工业废气二氧化硫的应用研究* *基金项目：固废资源化利用与节能建材国家重点实验室开放基金资助项目（SWR-2017-002）；新世纪优秀人才支持计划资助项目（NCET120967）；中央高校基本科研业务专项基金资助项目（2009QH03）。 Project supported by Open Funds of State Key Laboratory of Solid Waste Reuse for Building Materials (SWR-2017-002), New Century Excellent Talents in University (NCET120967), and Fundamental Research Funds for the Central Universities (2009QH03). 通讯作者：竹涛（1979—），男，博士，教授，所长，博士研究生导师，主要从事大气污染控制与固体废物资源化方面的研究。 竹涛1,2，王若男1，金鑫睿1，宋玉涵1，吕怡蓉1，张耕苑1 （1.中国矿业大学（北京）化学与环境工程学院，北京 100083； 2.固废资源化利用与节能建材国家重点实验室，北京 100041） 摘 要：氧化铝生产过程中会产生大量赤泥废渣，为了利用赤泥渣特殊的理化特性，达到以废治废和资源化循环利用的目的，本文采用山东铝业混合赤泥做原料，对其进行物相分析及单因素脱硫实验。通过分析温度、液固比、赤泥粒度、烟气浓度和pH对脱硫效率的影响，实现了操作条件最优化。结果表明：赤泥用于烟气脱硫时，脱硫效率可长时间维持在95%之上；温度为20℃、液固比12:1、赤泥粒度为0.178mm，pH大于4.5，一定范围内反应速率随浓度增大而增大。 关键词：赤泥；脱硫；理化特性；液固比；反应机理 Waste treatment by waste - study on the application of solid red mud for purification of sulphur dioxide from industrial waste gas Zhu Tao1,2, Wang Ruonan1, Jin Xinrui1, Song Yuhan1, Lv Yirong1, Zhang Gengyuan1 （1.School of Chemical and Environmental Engineering, China University of Mining and Technology(Beijing), Beijing 100083; 2. State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing 100041） Abstract: A lot of red mud residue will be produced in the production of alumina. In order to make full use of the special physical and chemical properties of red mud waste solid to complete waste recycling and resource reusing, this paper selected red mud as raw material for desulfurizing in the field of air pollution control. A series of experiments of physical analysis and single factor desulfurization experiments were carried out. By analyzing the influence of temperature, liquid-solid ratio, red mud particle size, smoke concentration and pH on desulfurization efficiency, the operation conditions were optimized. The results show the desulfurization efficiency can be maintained above 95% for a long time under reaction temperature of 20 ℃, liquid-solid ratio of 12:1, red mud particle size o