比赛不带动漫专题讲座.ppt

A Novel fuel-cell-assisted iron redox process for sulfur and energy recovery from sulfide wastes “Hubing Lake” Team Outlines Background Project details Environment Implication Market Advantages of project Publications Background  Energy shortage Environmental pollution Development of effective, stable, and feasible methods for sulfur and energy recovery from sulfide attains double advantages for the environment. Sulfide waste causes severe environmental pollution due to its toxicity, corrosivity, and malodorous property . Project details Content Title Overall reactions: Sulfide + O2 → S↓+ electricity Flow diagram of the FC-IR process Reactions in the oxidizing reactor: H2S+2Fe3+→S0↓+2Fe2+ +2H+ Reactions in the fuel cell: 2Fe2++1/2O2+2H+→2Fe3++H2O Identity Recovered Sulfur Coupling operation of the FC-IR system obtains sulfide removal efficiency of 99.90%, sulfur recovery efficiency of 78±8.3%, and columbic efficiency of 58.6±1.6%, respectively. Produced Electricity EDTA is more favorable than NTA as the chelate of Fe(III) . The system with EDTA achieves sulfur recovery efficiencies of 89.9±0.2% to 100±3.1% and Coulombic efficiencies of 46.3±13.2 % to 75.1±0.5 % . Content Title Content Title Fe (II) – EDTA process maintains high efficiency in the recycling operation, with Coulomb efficiency up to 80%. The biogas contains: H2S 2.4%,O2 0.6%,N2,CO2,CH4.H2 Application of this novel process in treating a H2S containing biogas Evaluation of system efficiency Sulfide removal efficiency 99.0% Sulfur recovery efficiency 78.0% Coulombic efficiency 78.6% Advantages of project Sulfide is removed at high efficiency and sulfur and electricity are recovered simultaneously. The problem related to chelating degradation is well controlled This process is practical in treating H2S-containing gases Environmental Implication H2S +O2 Electricity S（clean） Iron catalys